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2222材料工程  2018, Vol. 46 Issue (11): 51-56    DOI: 10.11868/j.issn.1001-4381.2017.001013
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
激光诱导法制备高质量铌酸钾纳米线及其发光性能
李瑞1, 刘立英2,*(), 姬宇航1, 王如志1, 杨炎翰1, 胡安明3, 白石3
1 北京工业大学 材料科学与工程学院, 北京 100124
2 北京工业大学 应用数理学院, 北京 100124
3 北京工业大学 激光工程研究院, 北京 100124
Preparation of High Quality Potassium Niobate Nanowires by Laser Induced Method and Its Luminescence Properties
Rui LI1, Li-ying LIU2,*(), Yu-hang JI1, Ru-zhi WANG1, Yan-han YANG1, An-ming HU3, Shi BAI3
1 College of Materials Science and Engineering, Beijing University of Technology, Beijing 100124, China
2 College of Applied Science, Beijing University of Technology, Beijing 100124, China
3 Institute of Laser Engineering, Beijing University of Technology, Beijing 100124, China
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摘要 

以KOH,Nb2O5为原料,通过激光诱导法成功地在常温常压条件下制备出直径均匀、结晶性良好的铌酸钾纳米线。产物经XRD,SEM,Raman和UV-Vis等技术进行表征,并研究铌酸钾纳米线的光吸收和光致发光性能。结果表明:激光诱导产物化学式为KNb3O8(空间群为Pmmm(47),为正交晶系),纳米线的生长机制为SLS机制。纳米线的带隙宽度为2.84eV,在436nm处有一较强的蓝色发光峰。

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李瑞
刘立英
姬宇航
王如志
杨炎翰
胡安明
白石
关键词 激光诱导铌酸钾纳米线生长机制带隙宽度光致发光    
Abstract

Under normal temperature and pressure conditions, potassium niobate nanowires with uniform diameter and good crystallinity were prepared by laser-induced method using KOH and Nb2O5 as raw materials. The samples were characterized by XRD, SEM, Raman and UV-Vis, the light absorption and photoluminescence properties of potassium niobate nanowires were studied. The results show that the chemical formula of laser-induced samples is KNb3O8 (the space group is Pmmm (47), which is orthorhombic system). The growth mechanism of nanowires is the SLS mechanism. The band gap of the prepared nanowires is 2.84eV, there is a strong blue emission peak at 436nm.

Key wordslaser induced    potassium niobate nanowire    growth mechanism    band gap    photoluminescence
收稿日期: 2017-08-10      出版日期: 2018-11-19
中图分类号:  O649  
基金资助:国家自然科学基金(51472010);国家自然科学基金(11774017);北京工业大学日新人才支持计划(0060000514117010);北京市留学人员科技项目择优资助重点类项目与北京市属高校高水平创新团队建设计划项目(IDHT20170502)
通讯作者: 刘立英     E-mail: liuliying@bjut.edu.cn
作者简介: 刘立英(1979-), 女, 高级实验师, 博士, 主要从事新型低维光电功能材料的结构设计、制备表征、性能分析及其物理机理探索的研究, 联系地址:北京市朝阳区平乐园100号北京工业大学(100124), E-mail:liuliying@bjut.edu.cn
引用本文:   
李瑞, 刘立英, 姬宇航, 王如志, 杨炎翰, 胡安明, 白石. 激光诱导法制备高质量铌酸钾纳米线及其发光性能[J]. 材料工程, 2018, 46(11): 51-56.
Rui LI, Li-ying LIU, Yu-hang JI, Ru-zhi WANG, Yan-han YANG, An-ming HU, Shi BAI. Preparation of High Quality Potassium Niobate Nanowires by Laser Induced Method and Its Luminescence Properties. Journal of Materials Engineering, 2018, 46(11): 51-56.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2017.001013      或      http://jme.biam.ac.cn/CN/Y2018/V46/I11/51
Fig.1  实验装置图
(a)405nm半导体激光器;(b)激光器电流对应功率
Fig.2  激光照射10min时的XRD(a)和Raman(b)图谱
Fig.3  反应10min时的SEM图
(a)KNb3O8纳米线;(b)带有催化剂的KNb3O8纳米线
Fig.4  SLS生长机制
Fig.5  照射时间为10min时的紫外-可见吸收光谱图
Fig.6  照射时间为10min时的PL图谱
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