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材料工程  2020, Vol. 48 Issue (6): 163-169    DOI: 10.11868/j.issn.1001-4381.2018.001110
  研究论文 本期目录 | 过刊浏览 | 高级检索 |
Fei氏方波对Ni-P合金镀层组成及其非晶化程度的调控作用
郭琪琪, 费敬银, 张嫚, 韩锡正, 赵利娜
西北工业大学 理学院, 西安 710129
Fei’s square wave regulation on composition and amorphization of Ni-P alloy coating
GUO Qi-qi, FEI Jing-yin, ZHANG Man, HAN Xi-zheng, ZHAO Li-na
College of Science, Northwestern Polytechnical University, Xi'an 710129, China
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摘要 为解决常规电沉积过程中无法获得耐蚀性优异的非晶态结构Ni-P合金镀层的问题,以快速镀Ni-P合金镀液为基础镀液,采用Fei氏方波电沉积法研究波形参数对Ni-P合金镀层非晶化过程的影响规律。采用扫描电子显微镜(SEM)表征Ni-P合金镀层的微观形貌,通过能谱分析(EDS)方法进行镀层P含量分析,用X射线衍射技术(XRD)考察镀层相结构的变化。优化的脉冲工艺参数为:平均电流密度15 A/dm2,逆向脉冲系数0.3,占空比0.6,频率1 Hz。研究表明:通过调整Fei氏方波参数,可电沉积出镀层表面完整、外观光亮、P含量最高可达17.93%(质量分数)、几乎没有金属晶体衍射峰的非晶态Ni-P合金镀层。
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郭琪琪
费敬银
张嫚
韩锡正
赵利娜
关键词 非晶化电沉积Fei氏方波高PNi-P合金    
Abstract:In order to solve the problem that the Ni-P alloy coating with an amorphous structure having excellent corrosion resistance cannot be obtained in the conventional electrodeposition process, Ni-P alloy coatings were prepared on the basis of a high-speed electroplating bath, and the law of influence of waveform parameters on the amorphization process of Ni-P alloy coatings was studied by using Fei’s square wave electrodeposition method. The micromorphologies of Ni-P alloy coatings were characterized by scanning electron microscopy (SEM) under different conditions. The P content of the coatings was analyzed by energy spectrum analysis (EDS). Structural changes of phase of the coatings were investigated by X-ray diffraction (XRD). The optimized pulse process parameters are: the average current density is 15 A/dm2, the inverse pulse coefficient is 0.3, the duty ratio is 0.6, and the frequency is 1 Hz. The results show that by adjusting Fei’s square wave pulse parameters, the fully amorphous Ni-P alloy coating can be electrodeposited, which has the features of high P content up to 17.93% (mass fraction), negligible nickel crystal diffraction peaks, and the smooth surface with a bright appearance as well.
Key wordsamorphization    electrodeposition    Fei&rsquo    s square wave    high P    nickel-phosphorus alloy
收稿日期: 2018-09-18      出版日期: 2020-06-15
中图分类号:  TG174.441  
通讯作者: 费敬银(1962-),男,副教授,博士,主要从事新型功能表面改性技术与应用研究,联系地址:陕西省西安市西北工业大学长安校区理学院(710129), jyfei@nwpu.edu.cn     E-mail: jyfei@nwpu.edu.cn
引用本文:   
郭琪琪, 费敬银, 张嫚, 韩锡正, 赵利娜. Fei氏方波对Ni-P合金镀层组成及其非晶化程度的调控作用[J]. 材料工程, 2020, 48(6): 163-169.
GUO Qi-qi, FEI Jing-yin, ZHANG Man, HAN Xi-zheng, ZHAO Li-na. Fei’s square wave regulation on composition and amorphization of Ni-P alloy coating. Journal of Materials Engineering, 2020, 48(6): 163-169.
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http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2018.001110      或      http://jme.biam.ac.cn/CN/Y2020/V48/I6/163
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