Please wait a minute...
 
材料工程  2015, Vol. 43 Issue (4): 59-65    DOI: 10.11868/j.issn.1001-4381.2015.04.011
  材料与工艺 本期目录 | 过刊浏览 | 高级检索 |
甲基硅油对有机硅防污涂层表界面特性的影响
巴淼, 张占平, 齐育红
大连海事大学 船机修造工程实验室, 辽宁 大连 116026
Influence of Methyl Silicone Oil on Surface and Interfacial Properties of Silicone Antifouling Coatings
BA Miao, ZHANG Zhan-ping, QI Yu-hong
Key Laboratory of Ship-machinery Maintenance & Manufacture, Dalian Maritime University, Dalian 116026, Liaoning, China
全文: PDF(3091 KB)  
输出: BibTeX | EndNote (RIS)      
摘要 以羟基封端的聚二甲基硅氧烷为主要成膜物,添加不同分子量和添加量的甲基硅油制备有机硅防污涂料。结果表明:甲基硅油的分子量越小、添加量越大,涂层的水接触角和二碘甲烷接触角越大,表面自由能越小;涂层的弹性模量随硅油分子量的减小而降低,在A组分中,硅油添加量占13%(质量分数,下同)时,弹性模量最小;附着生物的相对结合力随着硅油分子量的增加而增大,随着硅油含量的增加而降低;海水浸泡期间,硅油中的甲基与水分子发生氢键作用,从而使得甲基的峰位变宽,涂层的疏水性降低;所有涂层在空气中静置一年,只有添加分子量为1750甲基硅油的未浸泡海水涂层表面观测到硅油的渗出,且硅油渗出量与添加量成正比。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
巴淼
张占平
齐育红
关键词 有机硅甲基硅油涂层性能浸泡    
Abstract:The silicone antifouling, coating with hydroxy-terminated polydimethylsiloxane as main film,and with the addition of methyl silicone oil with different molecular weight and different content, was prepared. The results show that water contact angles and diiodomethane contact angles become larger, while surface free energy becomes smaller with decreasing the molecular weight and increasing the content of silicone oil; the elastic modulus of coating becomes lower with reducing the molecular weight and the elastic modulus reaches the mininum while the content of methyl silicone oil is 13%(mass fraction) in part A. The relative adhesion force of biofouling increases with the increasing of molecular weight and reduces with the increasing of content of silicone oil; during the process of coatings immersing in seawater, the-CH3 in silicone oil can take hydrogen bonding effect with H2O molecular, thus results in the range of methyl peak becomes lager in FTIR spectra, and the hydrophobicity of silicone coatings decreases; all coatings are allowed to stand in air for one year, only the non-immersion silicone coating with the addition of methyl silicone oil of 1750 molecular weight are found the exudation of silicone oil and the amount of exudation is proportional to the amount of the addition.
Key wordssilicone    methyl silicone oil    coating    property    immersion
收稿日期: 2013-12-10     
1:  O484.4  
  TB383  
基金资助:国家自然科学基金资助项目(51079011,51179018);交通运输部应用基础研究资助项目(2013329225330);总装预研基金资助项目(JZ12-58);大连海事大学船机修造工程交通行业重点实验室开放课题资助项目(CJXZ201304);中央高校基本科研业务费之大连海事大学优秀科技创新团队培育计划资助项目(3132014323)
通讯作者: 张占平(1963-),男,教授,从事海洋防腐防污材料研究工作,联系地址:辽宁省大连市大连海事大学交通运输装备与海洋工程学院(116026),zzp@dlmu.edu.cn     E-mail: zzp@dlmu.edu.cn
引用本文:   
巴淼, 张占平, 齐育红. 甲基硅油对有机硅防污涂层表界面特性的影响[J]. 材料工程, 2015, 43(4): 59-65.
BA Miao, ZHANG Zhan-ping, QI Yu-hong. Influence of Methyl Silicone Oil on Surface and Interfacial Properties of Silicone Antifouling Coatings. Journal of Materials Engineering, 2015, 43(4): 59-65.
链接本文:  
http://jme.biam.ac.cn/jme/CN/10.11868/j.issn.1001-4381.2015.04.011      或      http://jme.biam.ac.cn/jme/CN/Y2015/V43/I4/59
[1] 马世宁,张占平. 舰船防污涂层技术的发展现状与趋势[J].中国表面工程,2009,22(6):19-23.MA Shi-ning,ZHANG Zhan-ping. Development and future trends of antifouling coatings for ship[J]. China Surface Engineering,2009,22(6):19-23.
[2] VINCENT D M. Advances in environmentally benign coatings and adhesives[J]. Progress in Organic Coatings,1996,27(1):153-161.
[3] JOHN T,MAUREEN S,ADRIAN A. Inhibiting bacterial adhesion onto surfaces:the non-stick coating approach[J]. International Journal of Adhesion & Adhesives,2000,20(2):91-96.
[4] ELISABETE A,TERESA C D,ORLANDO S. Marine paints:the particular case of antifouling paints[J]. Progress in Organic Coatings,2007,59(1):2-20.
[5] 丁树丹,顾彩香,于阳,等. 船舶防污涂料的研究进展[J].中国水运,2011,(6):22-24.DING Shu-dan,GU Cai-xiang,YU Yang, et al. Progress in marine antifouling coatings[J].China Water Transport,2011,(6):22-24.
[6] BATTELLE. Ship's hull coated with antifouling silicone rubber[P].USA Patent:3702778,1972-11-14.
[7] 潘莹,张三平,周建龙,等. 有机硅低表面能防污涂料控制因素与研究进展[J].涂料工业,2009,39(12):58-61.PAN Ying, ZHANG San-ping, ZHOU Jian-long,et al. Controlling factors and progress of low surface energy silicone antifouling coatings[J]. Paint & Coatings Industry,2009,39(12):58-61.
[8] BRADY R F, SINGER I L. Mechanical factors favoring release from fouling release coatings[J]. Biofouling,2000,15(1-3):73-81.
[9] 程宇锋,蔡文俊,孙国亮.船舶低表面能防污涂料研究进展[J].化学工程师,2010,(9):36-41.CHENG Yu-feng,CAI Wen-jun,SUN Guo-liang. Development of shipping low surface energy antifouling paints[J]. Applied Chemical Industry,2010,(9):36-41.
[10] EVARISTE E,GACHON C M,CALLOW M E, et al. Development and characteristics of an adhesion bioassay for ectocarpoid algae[J]. Biofouling,2012,28(1):15-27.
[11] 田军,薛群基.有机硅涂层表面能对海生物附着的影响[J].海洋学报,1998,20(5):61-64. TIAN Jun,XUE Qun-ji. Adhesion of foulings on surface free energy of silicone rubber coatings[J]. Acta Oceanologica Sinica,1998,20(5):61-64.
[12] AFSAR A,ROCKY D N,STEINBERG P. The effect of foul-release coatings on the settlement and behaviour of cyprid larvae of the barnacle balanus amphitrite darwin[J]. Biofouling,2003,19(1):105-110.
[13] BRADY R F. Clean hulls without poisons:devising and testing non-toxic marine coatings[J]. Journal of Coatings Technology,2000,72(900):45-56.
[14] BRADY R F. A fracture mechanical analysis of fouling release from nontoxic antifouling coatings[J].Progress in Organic Coatings,2001,43:188-192.
[15] OWENS D K,WENDT R D. Liquid spreading on rough metal surfaces[J]. Mater Sci,1980,15:431-437.
[16] 王科,于雪艳,陈绍平,等. 硅油对低表面能有机硅防污涂料性能的影响[J].涂料工业,2009,39(5):39-46. WANG Ke,YU Xue-yan,CHEN Shao-ping, et al. Effect of silicone oil on properties of low surface energy silicone antifouling coatings[J]. Paint & Coatings Industry,2009,39(5):39-46.
[17] 桂泰江. 有机硅氟低表面能防污涂料的制备和表征[D].青岛:中国海洋大学,2008. GUI Tai-jiang. Preparation and characterization of the organic silicone/fluorine antifouling coatings with low surface energy[D].Qingdao:Ocean University of China,2008.
[18] 张招贵, 刘峰, 余政,等. 有机硅化合物化学[M].北京:化学工业出版社,2010. ZHANG Zhao-gui, LIU Feng, YU Zheng, et al. The Chemistry of Organic Silicone Compound[M]. Beijing:Chemical Industry Press,2010.
[1] 李敬勇, 刘涛, 郭宇文. 搅拌摩擦加工铝基复合材料的高温摩擦磨损性能[J]. 材料工程, 2015, 43(6): 21-25.
[2] 许天旱, 王荣, 冯耀荣, 雒设计, 王党会, 杨宝. 应力比对K55套管钻井钢疲劳裂纹扩展性能的影响[J]. 材料工程, 2015, 43(6): 79-84.
[3] 江陆, 孙新军, 李昭东, 雍岐龙, 王长军. 两相区回火温度对Mn-Mo系微合金钢亚稳奥氏体形成及力学性能的影响[J]. 材料工程, 2015, 43(5): 1-7.
[4] 杨可, 杨克, 包晔峰. 氮合金化堆焊硬面合金的耐腐蚀性能研究[J]. 材料工程, 2015, 43(5): 33-37.
[5] 李雪爱, 王春生, 韩喜江. 原位化学沉淀法制备Fe3O4-石墨复合材料的吸波性能[J]. 材料工程, 2015, 43(5): 44-49.
[6] 卢林刚, 陈英辉, 程哲, 杨守生, 邵高耸. 新型无卤膨胀/MH阻燃环氧树脂的制备及阻燃性能[J]. 材料工程, 2015, 43(5): 50-55.
[7] 万同, 杨光瑞, 张婕, 王彪. 柠檬酸醚酯增塑剂的合成及增塑聚乳酸[J]. 材料工程, 2015, 43(5): 67-74.
[8] 刘铭, 汝继刚, 臧金鑫, 张坤, 何维维, 王亮, 陈高红. 新型Al-Zn-Mg-Cu铝合金热稳定性研究[J]. 材料工程, 2015, 43(4): 13-18.
[9] 贺世美, 熊翔, 何利民. 新型Yb2SiO5环境障涂层1400℃高温氧化行为[J]. 材料工程, 2015, 43(4): 37-41.
[10] 查柏林, 高双林, 乔素磊, 黄定园, 袁小阳, 林浩. 超音速火焰喷涂参数及粉末粒度对WC-12Co涂层弹性模量的影响[J]. 材料工程, 2015, 43(4): 92-97.
[11] 马彦, 陈朝辉. 1800℃热处理对PIP法C/SiC复合材料结构和性能的影响[J]. 材料工程, 2015, 43(4): 98-101.
[12] 傅田, 李文亚, 杨夏炜, 李锦锋, 高大路. 搅拌摩擦点焊技术及其研究现状[J]. 材料工程, 2015, 43(4): 102-114.
[13] 张响, 陈招科, 熊翔. C/C-SiC复合材料表面ZrB2基陶瓷涂层的制备及高温烧结机理[J]. 材料工程, 2015, 43(3): 1-6.
[14] 彭建, 彭毅, 韩韡, 潘复生. 挤压温度对Mg-2Zn-Mn-0.5Nd镁合金组织和性能的影响[J]. 材料工程, 2015, 43(3): 23-27.
[15] 邹凯, 李蓉萍, 刘永生, 田磊, 冯松. Sb掺杂ZnTe薄膜结构及其光电性能[J]. 材料工程, 2015, 43(3): 35-41.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
版权所有 © 2015《材料工程》编辑部
地址:北京81信箱44分箱 邮政编码: 100095
电话:010-62496276 E-mail:matereng@biam.ac.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn