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2222材料工程  2015, Vol. 43 Issue (12): 45-51    DOI: 10.11868/j.issn.1001-4381.2015.12.008
  材料与工艺 本期目录 | 过刊浏览 | 高级检索 |
Al0.3CoCrFeNi高熵合金高压扭转过程中的组织结构演变
唐群华1, 廖晓舟2, 戴品强1,3,*()
1 福州大学 材料科学与工程学院, 福州 350116
2 悉尼大学 航空航天及机械与机电工程学院, 悉尼 NSW2006
3 福建工程学院 材料科学与工程学院, 福州 350116
Microstructure Evolution of Al0.3CoCrFeNi High-entropy Alloy During High-pressure Torsion
Qun-hua TANG1, Xiao-zhou LIAO2, Pin-qiang DAI1,3,*()
1 College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, China
2 School of Aerospace, Mechanical and Mechatronic Engineering, the University of Sydney, Sydney NSW2006, Australia
3 School of Materials Science and Engineering, Fujian University of Technology, Fuzhou 350116, China
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摘要 

对面心立方(FCC)结构的Al0.3CoCrFeNi高熵合金进行不同应变量的高压扭转实验,利用维氏硬度仪、电子背散射衍射、X射线衍射仪以及透射电镜系统分析变形引起的组织结构演变。结果表明:高压扭转过程中合金晶体结构并未发生改变,仍然保持为FCC结构,但引发其晶粒纳米化,平均晶粒尺寸达到30nm。晶粒细化主要是通过孪晶(包含初次孪晶与二次孪晶)、去孪晶(包含初次去孪晶与二次去孪晶)以及孪晶界分割晶粒的过程实现。孪晶和随后去孪晶的竞争作用导致孪晶宽度先减小后增大,初次孪晶和二次孪晶的最小宽度分别为2.7nm和0.9nm。

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关键词 高熵合金高压扭转晶粒细化孪晶去孪晶    
Abstract

An as-cast Al0.3CoCrFeNi high entropy alloy with face-centered cubic (FCC) structure was processed by high-pressure torsion (HPT) to different strain values. This deformation-induced microstructure evolution was investigated by using Vickers hardness, electron backscatter diffraction, X-ray diffraction and transmission electron microscopy. The results show that, during HPT processing,the crystal structure is not changed, remaining FCC structure, while nanocrystallization of grains is induced by HPT to 30nm of average grain size; grain refinement is achieved through twinning (including primary and secondary twinning), de-twinning (including primary and secondary de-twinning) and twin boundary subdivision; competition between twinning and de-twinning processes contributes to the decrease and subsequent increase in twin boundary spacing, while the minimum spacing of primary and secondary twins reach 2.7nm and 0.9nm, respectively.

Key wordshigh-entropy alloy    high-pressure torsion    grain refinement    twinning    de-twinning
收稿日期: 2015-05-30      出版日期: 2015-12-23
基金资助:福建省教育厅重点资助项目(JA11179)
通讯作者: 戴品强     E-mail: pqdai@126.com
作者简介: 戴品强(1963—),男,教授,博士,从事专业:纳米金属材料,联系地址:福建省福州市闽候大学城福州大学材料科学与工程学院309室(350116),E-mail:pqdai@126.com
引用本文:   
唐群华, 廖晓舟, 戴品强. Al0.3CoCrFeNi高熵合金高压扭转过程中的组织结构演变[J]. 材料工程, 2015, 43(12): 45-51.
Qun-hua TANG, Xiao-zhou LIAO, Pin-qiang DAI. Microstructure Evolution of Al0.3CoCrFeNi High-entropy Alloy During High-pressure Torsion. Journal of Materials Engineering, 2015, 43(12): 45-51.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2015.12.008      或      http://jme.biam.ac.cn/CN/Y2015/V43/I12/45
Fig.1  维氏硬度与等效应变的关系
Fig.2  铸态样品的显微组织
(a)OM图;(b)XRD图
Fig.3  变形阶段I样品的显微组织
(a)TEM像及SAED花样;(b)〈011〉 HRTEM像
Fig.4  变形阶段II样品的显微组织
(a)TEM像及SAED花样;(b)〈011〉 HRTEM像和箭头位置的IFFT图谱;(c)对应图4(b)中长方形区域的IFFT图
Fig.5  变形阶段III样品的显微组织
(a)TEM像和箭头位置的〈011〉 HRTEM像;(b)包含初次孪生和二次孪生的纳米晶TEM像;(c)对应图5(b)中黑色长方形区域的〈011〉 HRTEM像;(d)对应图5(b)中白色长方形区域的〈011〉 HRTEM像
Fig.6  变形阶段IV样品的显微组织和晶粒尺寸分布
(a)TEM像及SAED花样;(b)晶粒尺寸分布图
Fig.7  HPT高熵合金组织演变示意图
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