20钢强流脉冲电子束表面合金化的微观组织和性能

doi:10.11868/j.issn.1001-4381.2016.000961

摘要
图/表
参考文献
相关文章
Metrics

全文: PDF(4809 KB)

HTML ( 16 )
输出: BibTeX | EndNote (RIS)

摘要

为改善20钢件的表面性能，利用强流脉冲电子束（HCPEB）技术与预置涂层相结合的技术在20钢表面合金化Cr元素以获得高性能的合金复合改性层。利用X射线衍射、金相显微镜、扫描电子显微镜、透射电子显微镜、维氏硬度计以及多功能微机电化学分析仪对合金化层的显微组织以及性能进行研究。结果表明：20钢经过HCPEB辐照合金化后，形成了厚度约为4~6μm的合金化改性层，Cr元素在样品表层发生了固溶和扩散。部分渗碳体在辐照诱发的应力作用下出现弯折、粒化等现象，并在基体溶解与Cr结合析出颗粒细小弥散的Cr₂₃C₆增强相。HCPEB辐照合金化后材料表层显微硬度提高了35%，腐蚀电流密度降低了1个数量级。

	服务

	把本文推荐给朋友
	加入引用管理器
	E-mail Alert
	RSS
	作者相关文章
	郑欢欢
	刘鑫禹
	陈亚楠
	张从林
	吕鹏
	蔡杰
	关庆丰

关键词 ：电子束合金化, 表面强化, 微观组织, 显微硬度, 耐蚀性

Abstract：

To improve the surface properties of 20 steel, the chromium element was alloyed on 20 steel by high current pulsed electron beam (HCPEB) with pre-coating to obtain a high quality of alloyed layers.Microstructure and properties of the alloying layer were studied by means of XRD, OM, SEM, TEM and multi-purpose microcomputer electrochemistry analyzer. The results show that, after HCPEB alloying, the formation of an alloyed layer with the depth of about 4-6μm on the surface is observed. The solid solution and diffusion of Cr element occurs on the surface of the substrate.Bending and granulating occur on part of cementite under bending stress induced by HCPEB irradiation, the C atoms generated by the dissolution of the cementite combine with the chromium to form a small amount of nanograined carbide Cr₂₃C₆. After HCPEB alloying, the surface microhardness increases by 35% and corrosion current density reduces one order of magnitude than original sample.

Key words： alloyed electronic beam surface strengthening microstructure micro-hardness corrosion resis-tance

收稿日期: 2016-08-10 出版日期: 2018-07-20

中图分类号:

TB31

基金资助:国家自然科学基金青年项目(51601071);国家自然科学基金青年项目(51601072);三束材料改性教育部重点实验室开放课题(LABKF1504);江苏省自然科学基金青年基金(BK20160530)

通讯作者: 关庆丰 E-mail: guanqf@ujs.edu.cn

作者简介: 关庆丰(1963-), 男, 教授, 博士生导师, 主要从事载能束表面改性技术及微结构方面研究工作, 联系地址:江苏省镇江市京口区学府路301号江苏大学材料科学与工程学院(212013), E-mail:guanqf@ujs.edu.cn

引用本文:

郑欢欢, 刘鑫禹, 陈亚楠, 张从林, 吕鹏, 蔡杰, 关庆丰. 20钢强流脉冲电子束表面合金化的微观组织和性能[J]. 材料工程, 2018, 46(7): 127-135.
Huan-huan ZHENG, Xin-yu LIU, Ya-nan CHEN, Cong-lin ZHANG, Peng LYU, Jie CAI, Qing-feng GUAN. Microstructure and Properties of High Current Pulsed Electron Beam Surface Alloying on 20 Steel. Journal of Materials Engineering, 2018, 46(7): 127-135.

链接本文:

http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.000961 或 http://jme.biam.ac.cn/CN/Y2018/V46/I7/127

Fig.1 合金化层的X射线衍射分析

Fig.2 20钢HCPEB合金化前后的金相形貌
(a)20钢；(b)10次脉冲；(c)20次脉冲；(d)30次脉冲

Fig.3 HCPEB合金化样品表层SEM图及其EDS定量分析
(a)10次脉冲；(b)20次脉冲；(c)30次脉冲；(d)表面Cr元素的EDS定量分析

Fig.4 HCPEB合金化样品的截面SEM图(1)及线扫描分析(2)
(a)20次脉冲；(b)30次脉冲

Fig.5 原始样品(a)及辐照10次合金化样品((b)~(d))TEM图

Fig.6 20次合金化样品的TEM图
(a)渗碳体；(b)细小析出相

Fig.7 合金化样品表面铁素体的TEM图
(a)10次脉冲；(b)20次脉冲；(c)30次脉冲

Fig.8 合金化样品的表面显微硬度

Fig.9 20次合金化样品的截面显微硬度

Fig.10 合金化前后20钢样品的极化曲线

Table 1 电化学腐蚀性能测量结果

1	SUNG H K , SHIN S Y , HWANG B , et al. Effects of rolling and cooling conditions on microstructure and tensile and Charpy impact properties of ultra-low-carbon high-strength bainitic steels[J]. Metallurgical and Materials Transactions A, 2011, 42 (7): 1827- 1835. doi: 10.1007/s11661-010-0590-y
2	刘靖, 鹿守理. 低碳钢组织与力学性能关系[J]. 北京科技大学学报, 2002, 24 (2): 208- 210.
2	LIU J , LU S L . Relationship between microstructure and properties in low carbon steel[J]. Journal of University of Science and Technology Beijing, 2002, 24 (2): 208- 210.
3	YANG K , GOU H , ZHANG B , et al. Microstructures and fracture features of cold-rolled low carbon steel sheet after annealing and mechanical stress concurrently loaded[J]. Materials Science and Engineering:A, 2009, 502 (1): 126- 130.
4	HUANG S J , SEMENOV V I , SHUSTER L S , et al. Tribological properties of the low-carbon steels with different micro-structure processed by heat treatment and severe plastic deformation[J]. Wear, 2011, 271 (5): 705- 711.
5	WANG Z B , LU J , LU K . Wear and corrosion properties of a low carbon steel processed by means of SMAT followed by lower temperature chromizing treatment[J]. Surface and Coatings Technology, 2006, 201 (6): 2796- 2801. doi: 10.1016/j.surfcoat.2006.05.019
6	王松, 李晖, 许洪斌, 等. 基于高能束的表面合金化研究进展[J]. 南方金属, 2013, 194 (5): 1- 4.
6	WANG S , LI H , XU H B , et al. Research evolution of surface alloying by high energy beams[J]. Southern Metals, 2013, 194 (5): 1- 4.
7	张林伟, 余玖明, 张旭, 等. 脉冲爆炸-等离子体技术处理对T8钢表层组织和性能的影响[J]. 材料工程, 2017, 45 (5): 100- 105. doi: 10.11868/j.issn.1001-4381.2015.000999
7	ZHANG L W , YU J M , ZHANG X , et al. Effect of pulse detonation-plasma technology treatment on structure of surface layer and performance of T8 steel[J]. Journal of Materials Engineering, 2017, 45 (5): 100- 105. doi: 10.11868/j.issn.1001-4381.2015.000999
8	符寒光, 姚书典. 铸件表面合金化工艺研究的进展[J]. 现代铸铁, 1996, (1): 30- 32.
8	FU H G , YAO S D . Progress in study on process of surface alloying of castings[J]. Modern Cast Iron, 1996, (1): 30- 32.
9	SHEN L , WANG L , WANG Y , et al. Plasma nitriding of AlSi 304 austenitic stainless steel with pre-shot peening[J]. Surface and Coatings Technology, 2010, 204 (20): 3222- 3227. doi: 10.1016/j.surfcoat.2010.03.018
10	QIN L , YANG K , LIU C , et al. Enhanced plasma boriding with molybdenum using double glow plasma surface alloying technique[J]. Materials Letters, 2012, 82, 127- 129. doi: 10.1016/j.matlet.2012.05.069
11	LIU C , CHEN S , SHANG L , et al. Microstructure and property of laser gas nitriding on gamma-TiAl alloy[J]. Chinese Journal of Lasers, 2002, 29 (3): 277- 280.
12	PROSKUROVSKY D I , ROTSHTEIN V P , OZUR G E , et al. Pulsed electron-beam technology for surface modification of metallic materials[J]. Journal of Vacuum Science & Technology A, 1998, 16 (4): 2480- 2488.
13	POGREBNJAK A D , BRATUSHKA S , BOYKO V I , et al. A review of mixing processes in Ta/Fe and Mo/Fe systems treated by high current electron beams[J]. Nuclear Instruments and Methods in Physics Research Section B:Beam Interactions with Materials and Atoms, 1998, 145 (3): 373- 390. doi: 10.1016/S0168-583X(98)00417-0
14	WANG S S , PENG D L , CHANG L , et al. Enhanced mechanical properties induced by refined heat treatment for 9Cr-0.5Mo-1.8W martensitic heat resistant steel[J]. Materials & Design, 2013, 50, 174- 180.
15	IVANOVA Y F , ROTSHTEINA V P . Pulsed electron-beam treatment of WC-TiC-Co hard-alloy cutting tools:wear resistance and microstructural evolution[J]. Surface and Coatings Technology, 2000, 125 (1/3): 251- 256.
16	吴爱民. 模具钢电子束表面改性及应用基础研究[D]. 大连: 大连理工大学, 2002.
16	WU A M. Surface modification of die steels by high current pulsed electron beam[D]. Dalian: Dalian University of Technology, 2002.
17	秦颖, 吴爱民, 邹建新, 等. 强流脉冲电子束表面改性的物理模型及数值模拟[J]. 强激光与粒子束, 2003, 15 (7): 701- 704.
17	QIN Y , WU A M , ZOU J X , et al. Physical model and numerical simulation of intense pulsed electron beam surface modification[J]. High Power Laser and Particle Beams, 2003, 15 (7): 701- 704.
18	杨盛志, 王晓彤, 李艳, 等. 强流脉冲电子束作用下镍基高温合金GH4169的微观结构及腐蚀性能[J]. 机械工程学报, 2015, 51 (12): 50- 56.
18	YANG S Z , WANG X T , LI Y , et al. Microstructure and corrosion resistance on the surface of nickel-based superalloy GH4169 treated by high-current pulsed electron beam[J]. Journal of Mechanical Engineering, 2015, 51 (12): 50- 56.
19	邹慧, 关庆丰, 张庆瑜, 等. 利用强流脉冲电子束对45^#钢进行表面改性[J]. 吉林大学学报:工学版, 2004, 34 (1): 127- 131.
19	ZOU H , GUAN Q F , ZHANG Q Y , et al. Surface modification of 45^#steel by high-current pulsed electron beam[J]. Journal of Jilin University of Technology:Natural Science Edition, 2004, 34 (1): 127- 131.
20	ZOU J , ZHANG K , DONG C , et al. Selective surface purification via crater eruption under pulsed electron beam irradiation[J]. Applied Physics Letters, 2006, 89 (4): 041913. doi: 10.1063/1.2234306
21	胡丽华, 张雷, 许立宁, 等. Cr含量对低合金耐蚀管线钢焊接接头组织和性能的影响[J]. 材料热处理学报, 2010, 31 (3): 92- 96.
21	HU L H , ZHANG L , XU L N , et al. Effects of Cr content on microstructure and properties of low alloy corrosion resistant pipeline steel weld joints[J]. Transactions of Materials and Heat Treatment, 2010, 31 (3): 92- 96.
22	刘明, 程学群, 李晓刚, 等. Cr合金化对HRB400钢筋腐蚀行为的研究[J]. 腐蚀科学与防护技术, 2015, 27 (6): 559- 564.
22	LIU M , CHENG X Q , LI X G , et al. Corrosion behavior of Cr modified HRB400 steel rebar in 2%NaCl solution[J]. Corrosion Science and Protection Technology, 2015, 27 (6): 559- 564.
23	关庆丰. 强流脉冲电子束作用下金属材料的微观结构状态[D]. 长春: 吉林大学, 2005.
23	GUAN Q F. Microstructures of metal materials induced by high current pulsed electron beam[D]. Changchun: Jilin University, 2005.
24	DONG C , WU A , HAO S , et al. Surface treatment by high current pulsed electron beam[J]. Surface and Coatings Technology, 2003, 163, 620- 624.
25	关庆丰, 陈波, 张庆瑜, 等. 强流脉冲电子束辐照下单晶铝中的堆垛层错四面体[J]. 物理学报, 2008, 57 (1): 392- 397. doi: 10.7498/aps.57.392
25	GUAN Q F , CHEN B , ZHANG Q Y , et al. Stacking fault tetrahedral in single-crystal aluminum induced by high-current pulsed electron beam[J]. Acta Physica Sinica, 2008, 57 (1): 392- 397. doi: 10.7498/aps.57.392
26	季乐, 杨盛志, 蔡杰, 等. 强流脉冲电子束辐照诱发纯钼表面的损伤效应及结构缺陷[J]. 物理学报, 2013, 62 (23): 236103- 236110. doi: 10.7498/aps.62.236103
26	JI L , YANG S Z , CAI J , et al. Damage and structural defects in the surface lager of pure molybdenum induced by high-current pulsed electron beam[J]. Acta Physica Sinica, 2013, 62 (23): 236103- 236110. doi: 10.7498/aps.62.236103
27	HANSEN N , MEHL R F . New discoveries in deformed metals[J]. Metallurgical and Materials Transactions A, 2001, 32 (12): 2917- 2935. doi: 10.1007/s11661-001-0167-x
28	WANG X , HAN X G , LEI M K , et al. Effect of high-intensity pulsed ion beams irradiation on corrosion resistance of 316L stainless steel[J]. Materials Science and Engineering:A, 2007, 457 (1): 84- 89.
29	史子木, 张在强, 牛丽媛, 等. 强流脉冲电子束作用下AlSi 304L奥氏体不锈钢的微观结构与腐蚀性能[J]. 高压物理学报, 2014, 28 (5): 597- 603. doi: 10.11858/gywlxb.2014.05.014
29	SHI Z M , ZHANG Z Q , NIU L Y , et al. Microstructures and corrosion property of AlSi 304L austenitic stainless steel irradiated by high-current pulsed electron beam[J]. Chinese Journal of High Pressure Physics, 2014, 28 (5): 597- 603. doi: 10.11858/gywlxb.2014.05.014

[1]	许家豪, 汪选国, 姚振华. 粉末冶金制备工艺对TiC增强高铬铸铁基复合材料性能的影响[J]. 材料工程, 2022, 50(9): 105-112.
[2]	朱阳阳, 李晓延, 张伟栋, 张虎, 何溪. 全Cu₃Sn焊点在高温时效下的组织及力学性能[J]. 材料工程, 2022, 50(9): 169-176.
[3]	张昌青, 王树文, 罗德春, 师文辰, 刘晓, 崔国胜, 陈波阳, 辛舟, 芮执元. 热电耦合对铝/钢连续驱动摩擦焊接头组织的影响机理[J]. 材料工程, 2022, 50(5): 35-42.
[4]	翟海民, 马旭, 袁花妍, 欧梦静, 李文生. 内生非晶复合材料组织与力学性能调控研究进展[J]. 材料工程, 2022, 50(5): 78-89.
[5]	安强, 祁文军, 左小刚. TA15钛合金表面原位合成TiC增强钛基激光熔覆层的组织与耐磨性[J]. 材料工程, 2022, 50(4): 139-146.
[6]	孙琦迪, 杨蔚涛, 郝庆国, 关肖虎, 章斌, 杨旗. 低周疲劳变形过程中Fe-33Mn-4Si合金钢的微观组织演变[J]. 材料工程, 2022, 50(4): 162-171.
[7]	姜明明, 孙树峰, 王津, 王萍萍, 孙晓雨, 邵晶, 刘纪新, 曹爱霞, 孙维丽, 陈希章. 激光熔覆制备高熵合金涂层耐磨性研究进展[J]. 材料工程, 2022, 50(3): 18-32.
[8]	计植耀, 马跃, 王清, 董闯. 高性能软磁合金的研究进展[J]. 材料工程, 2022, 50(3): 69-80.
[9]	余晖, 任军超, 杨鑫, 郭舒龙, 余炜, 冯建航, 殷福星, 辛光善. Zn层添加AZ31/7075合金复合成形工艺及组织与性能研究[J]. 材料工程, 2022, 50(3): 157-165.
[10]	陈高红, 张月, 李应权, 刘建华, 于美. 缓蚀剂组合的容器负载方式对铝合金涂层耐蚀性能的影响[J]. 材料工程, 2022, 50(2): 153-163.
[11]	孙辉, 武会宾, 张游游, 袁睿, 张志慧. Cr含量对CrMnFeNi系高熵合金腐蚀行为的影响[J]. 材料工程, 2022, 50(11): 127-134.
[12]	陈维平, 陈焕达, 褚晨亮, 付志强. 粉末冶金(FeNiMnAl_x)₅₀Cu₅₀中熵合金的微观组织与力学性能[J]. 材料工程, 2022, 50(10): 55-62.
[13]	邵震, 崔雷, 王东坡, 陈永亮, 胡正根, 王非凡. 几何参数对2219铝合金拉拔式摩擦塞补焊接头微观组织及力学性能的影响[J]. 材料工程, 2022, 50(1): 25-32.
[14]	吕彦龙, 贺建超, 侯金保, 张博贤. 热处理对TiAl/Ti₂AlNb放电等离子扩散焊接头微观组织与力学性能的影响[J]. 材料工程, 2021, 49(9): 87-93.
[15]	李安庆, 张立华, 蒋日鹏, 李晓谦, 张昀. 冷却速度及超声振动协同作用对7085铝合金凝固组织及力学性能的影响[J]. 材料工程, 2021, 49(8): 63-71.

Viewed

Full text

Abstract

Cited

Shared

Discussed