快速电沉积法制备镍基金刚石复合镀层

doi:10.11868/j.issn.1001-4381.2016.10.004

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摘要为解决镍基金刚石复合电沉积过程中普遍存在镀层沉积速率慢、镀层内应力大的问题，本工作以新型高速Ni镀液为基础，考查了镀液中去应力添加剂含量、工艺参数，以及金刚石含量对镀层内应力影响的规律，并对复合镀层的微观形貌进行了表征。优选出了可以在30A/dm²的高阴极电流密度下快速电沉积低应力镍基金刚石复合镀层的镀液组成及工艺条件。结果表明：当镀液组成为十二烷基硫酸钠0.5g/L，乙酸铵3g/L，柠檬酸三钠1.5g/L，金刚石微粒浓度30g/L；施镀条件为pH值3~4，温度50℃时，制得的复合镀层内应力最低。

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	张闫
	费敬银
	李倍
	赵非凡
	彭秋艳

关键词 ：快速电镀, 复合电沉积, 内应力, 镍基金刚石复合镀层, 添加剂

Abstract：Nickel/diamond composite coatings were prepared on the basis of a new high speed electroplating bath. The influence of additives, plating parameters and diamond concentration on internal stress was investigated in order to find the solution to decrease the stress introduced by high current density; the micro morphology of the coatings were observed by SEM. The bath and depositing parameters were optimized that thick nickel/diamond composite coatings with low internal stress can be high speed electroplated with a high cathode current density of 30A/dm². The results show that when plated with bath composition and parameters as follows: sodium dodecyl sulfate 0.5g/L, ammonium acetate 3g/L, sodium citrate 1.5g/L, diamond particles 30g/L; pH value 3-4, temperature 50℃, the composite coatings prepared in high speed have the lowest internal stress.

Key words： high speed electroplating electro co-depositing internal stress nickel/diamond composite coating additive

收稿日期: 2016-02-01 出版日期: 2016-10-20

中图分类号:

TQ153.2

通讯作者: 费敬银(1962-),男,博士,副教授,主要从事新型功能表面改性技术与应用研究,联系地址:陕西省西安市西北工业大学长安校区理学院(710129),E-mail:jyfei@nwpu.edu.cn E-mail: jyfei@nwpu.edu.cn

引用本文:

张闫, 费敬银, 李倍, 赵非凡, 彭秋艳. 快速电沉积法制备镍基金刚石复合镀层[J]. 材料工程, 2016, 44(10): 24-32.
ZHANG Yan, FEI Jing-yin, LI Bei, ZHAO Fei-fan, PENG Qiu-yan. Nickel/Diamond Composite Coating Prepared by High Speed Electrodeposition. Journal of Materials Engineering, 2016, 44(10): 24-32.

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http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.10.004 或 http://jme.biam.ac.cn/CN/Y2016/V44/I10/24

[1] OMIDVAR H, SAJJADNEJAD M, STREMSDOERFER G, et al. Composite NiB-graphite and NiB-PTFE surface coatings deposited by the dynamic chemical plating technique[J]. Materials and Manufacturing Processes, 2016, 31(1):24-30.
[2] 王红星, 谈淑咏, 刘秉毅, 等. 纳米SiC浓度对Ni/纳米MoS₂基复合镀层结构和耐磨性能的影响[J]. 材料工程, 2015, 43(10):60-65. WANG H X, TAN S Y, LIU B Y, et al. Effect of nano-SiC content on microstructure and wear resistance of Ni/nano-MoS₂ based composite coating[J]. Journal of Materials Engineering, 2015, 43(10):60-65.
[3] 丁水, 张凯锋, 王国峰. 电沉积ZrO₂/Ni纳米复合材料低温高应变速率超塑性的研究[J]. 航空材料学报, 2008, 28(3):34-38. DING S, ZHANG K F, WANG G F. Research on low temperature and high strain rate superplasticity of ZrO₂/Ni nanocomposite produced by electrodeposition[J]. Journal of Aeronautical Materials, 2008, 28(3):34-38.
[4] MEHEDI M A, BHADHON K M H, HAQUE M N. Improved wear resistance of Al-Mg alloy with SiC and Al₂O₃ particle reinforcement[J]. Journal of the Minerals,Metals & Materials, 2016, 68(1):300-303.
[5] ARUNA S T, SELVI V E, GRIPS V K W, et al. Corrosion-and wear-resistant properties of Ni-Al₂O₃ composite coatings containing various forms of alumina[J]. Journal of Applied Electrochemistry, 2011, 41(4):461-468.
[6] 李国禄, 王海斗, 徐滨士, 等. 空间原子氧辐照对电刷镀Ni/MoS₂-C镀层组织结构及摩擦学性能的影响[J]. 材料工程, 2014,(2):24-28. LI G L,WANG H D,XU B S, et al. Effects of space atomic oxygen irradiation on the structure and tribological properties of Ni/MoS₂-C coating by electricity brush plating[J]. Journal of Materials Engineering, 2014,(2):24-28.
[7] 万冰华, 费敬银, 冯光勇, 等. Zn-Co-TiO₂纳米复合镀层的光生阴极保护特性[J]. 中国腐蚀与防护学报, 2012, 32(4):327-332. WAN B H, FEI J Y, FENG G Y, et al. Photogenerated cathode protection properties of Zn-Co-TiO₂ nanocomposite coatings[J]. Journal of Chinese Society for Corrosion and Protection, 2012, 32(4):327-332.
[8] TSUBOTA T, TANⅡ S, ISHIDA T, et al. Composite electroplating of Ni and surface-modified diamond particles with silane coupling regent[J]. Diamond and Related Materials, 2005, 14(3-7):608-612.
[9] LUKSCHANDEL J,MEYER J. Nickel-diamond-coated saw wire with improved anchoring of the diamond particles[P]. USA Patent:6322686, 2003-1-31.
[10] 亓曾笃. 金刚石的耐热性[J]. 工业金刚石, 2001,(1):14-15. QI Z D. Heat resistance of diamond[J]. Industrial Diamond, 2001,(1):14-15.
[11] ZHAO Z, DU L, XU Z, et al. Effects of ultrasonic agitation on adhesion strength of micro electroforming Ni layer on Cu substrate[J]. Ultrasonics Sonochemistry, 2016, 29:1-10.
[12] PATHAK S, GUINARD M, VERNOOIJ M G C, et al. Influence of lower current densities on the residual stress and structure of thick nickel electrodeposits[J]. Surface & Coatings Technology, 2011, 205(12):3651-3657.
[13] KENDRICK R J, WATSON S A. Bath and method for electroforming and electrodepositing nickel[P]. USA Patent:3326782, 1967-1-20.
[14] HUANG W, ZHAO Y, WANG X. Preparing a high-particle-content Ni/diamond composite coating with strong abrasive ability[J]. Surface & Coatings Technology, 2013, 235:489-494.
[15] 王美娟. Ni-金刚石复合镀层的制备及Ni电结晶初期行为的研究[D].长沙:中南大学, 2013. WANG M J. Research on the preparation of Ni-diamond composite plating and initial behavior of nickel electrocrystallization[D]. Changsha:Central South University, 2013.
[16] LEE E C, CHOI J W. A study on the mechanism of formation of electrocodeposited Ni-diamond coatings[J]. Surface & Coatings Technology, 2001, 148(2-3):234-240.
[17] 张午花, 费敬银, 骆立立, 等. 脉冲电沉积高速Ni工艺研究[J]. 中国腐蚀与防护学报, 2013, 33(4):317-324. ZHANG W H, FEI J Y, LUO L L, et al. High speed pulse electro plating process of nickel[J]. Journal of Chinese Society for Corrosion and Protection, 2013, 33(4):317-324.
[18] 林西华, 费敬银, 骆立立, 等. 甲基磺酸盐快速镀镍工艺参数对镀层内应力的影响[J]. 材料保护, 2014, 47(8):10-14. LIN X H, FEI J Y, LUO L L, et al. Effects of fast electrodepositing parameters from methanesulfonate solution methanesulfonate solution[J]. Journal of Materials Protection, 2014, 47(8);10-14.
[19] STONEY G G. The tension of metallic films deposited by electrolysis[J]. Proceedings of the Royal Society of London Series A, 1909, 82(553):172-175.
[20] 赵平堂. 氨基磺酸高速镀镍工艺的应用[J]. 材料保护, 2002, 35(3):51. ZHAO P T. High speed depositing nickel from sulfamate[J]. Journal of Materials Protection, 2002, 35(3):51.
[21] LIAO L, LIU W, XIAO X. The influence of sodium diphenylamine sulfonate on the electrodeposition of Mg-Ni alloy and its electrochemical characteristics[J]. Journal of Electroanalytical Chemistry, 2004, 566(2):341-350.
[22] KARTAL M, UYSAL M, GUL H, et al. Effect of surfactant concentration in the electrolyte on the tribological properties of nickel-tungsten carbide composite coatings produced by pulse electro co-deposition[J]. Applied Surface Science, 2015, 354, Part B:328-336.
[23] 杨建文, 邓型深, 徐浩森, 等. 4种羧酸盐配位剂对装饰性三价铬电镀的作用[J]. 材料保护, 2009, 42(6):39-41. YANG J W, DENG X S, XU H S, et al. Influence of 4 carboxylate complexing agent on depositing decorative trivalent chromium[J]. Journal of Materials Protection, 2009, 42(6):39-41.
[24] 李延伟, 姚金环, 杨哲龙. 氨基磺酸盐镀镍过程中内应力产生及变化的因素与机理[J]. 材料保护, 2008, 41(10):34-36. LI Y W, YAO J H, YANG Z L. Factors and mechanisms of internal stress change during plating nickel in sulfamate[J]. Journal of Materials Protection, 2008, 41(10):34-36.
[25] TERZIEVA V, FRANSAER J, CELIS J P. Codeposition of hydrophilic and hydrophobic silica with copper from acid copper sulfate baths[J]. Journal of the Electrochemical Society, 1999, 147(1):198-202.

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