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2222材料工程  2016, Vol. 44 Issue (11): 51-55    DOI: 10.11868/j.issn.1001-4381.2016.11.008
  材料与工艺 本期目录 | 过刊浏览 | 高级检索 |
石蜡/TiO2/活性炭复合相变材料的制备及其性能
郝勇敢, 邵先坤, 唐海娣, 汪涛, 刘佳佳, 李本侠()
安徽理工大学 材料科学与工程学院, 安徽 淮南 232001
Preparation and Properties of Paraffin/TiO2/Active-carbon Composite Phase Change Materials
Yong-gan HAO, Xian-kun SHAO, Hai-di TANG, Tao WANG, Jia-jia LIU, Ben-xia LI()
School of Materials Science and Engineering, Anhui University of Science & Technology, Huainan 232001, Anhui, China
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摘要 

以石蜡作为相变物质、二氧化钛(TiO2)作为基体材料,添加少量活性炭提高其热导率,通过微乳液法制备出新型石蜡/TiO2/活性炭复合相变材料。利用XRD,SEM,TGA,DSC对材料的组成、形貌和性质分别进行表征,并对材料相变过程中的形状稳定性进行测试。结果表明:石蜡被TiO2有效封装,保证了材料的定形相变特征;此外该复合材料还表现出超疏水性质。这些多功能特性将使其作为多功能涂料或其他添加剂在节能建筑中具有重要的应用价值。

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郝勇敢
邵先坤
唐海娣
汪涛
刘佳佳
李本侠
关键词 石蜡二氧化钛活性炭相变材料微乳液法    
Abstract

A novel composite phase change materials (PCMs) of paraffin/TiO2/active-carbon was prepared by a microemulsion method, where paraffin acted as a PCM and titanium dioxide (TiO2) as matrix material, and a small amount of active carbon was added to improve the thermal conductivity. The compositions, morphology and thermal properties of the paraffin/TiO2/active-carbon composite PCMs were characterized by XRD, SEM, TGA and DSC respectively. The shape stability during phase change process of this composite was also tested. The results show that paraffin is well encapsulated by TiO2 matrix, and thus exhibiting excellent shape-stabilized phase change feature. Besides, this composite PCM also presents superhydrophobic property. Therefore, these multifunctional features will endow PCMs with important application potential in energy efficient buildings.

Key wordsparaffin    titanium dioxide    active carbon    phase change material    microemulsion method
收稿日期: 2015-03-19      出版日期: 2016-11-22
中图分类号:  TB333  
基金资助:国家自然科学基金资助项目(21001003);中国博士后科学基金面上项目(2014M551789)
通讯作者: 李本侠     E-mail: bxli@aust.edu.cn
作者简介: 李本侠(1980-), 女, 博士, 教授, 研究方向:新型功能纳米材料, 联系地址:安徽省淮南市舜耕中路168号安徽理工大学材料科学与工程学院(232001), E-mail:bxli@aust.edu.cn
引用本文:   
郝勇敢, 邵先坤, 唐海娣, 汪涛, 刘佳佳, 李本侠. 石蜡/TiO2/活性炭复合相变材料的制备及其性能[J]. 材料工程, 2016, 44(11): 51-55.
Yong-gan HAO, Xian-kun SHAO, Hai-di TANG, Tao WANG, Jia-jia LIU, Ben-xia LI. Preparation and Properties of Paraffin/TiO2/Active-carbon Composite Phase Change Materials. Journal of Materials Engineering, 2016, 44(11): 51-55.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.11.008      或      http://jme.biam.ac.cn/CN/Y2016/V44/I11/51
Fig.1  纯石蜡(a)和石蜡/TiO2/活性炭复合相变材料(b)的XRD图谱
Fig.2  石蜡/TiO2复合相变材料(a)和石蜡/TiO2/活性炭复合相变材料(b)的FE-SEM照片
Fig.3  纯石蜡和石蜡/TiO2/活性炭复合PCMs的热重分析(TGA)曲线
Fig.4  纯石蜡(a)和石蜡/TiO2/活性炭复合PCMs (b)的DSC曲线
Fig.5  石蜡/TiO2复合相变材料(a),石蜡/TiO2/活性炭复合相变材料(b)和纯石蜡(c)的粉末样品在80℃下加热不同时间的照片
Fig.6  石蜡/TiO2复合相变材料(a),石蜡/TiO2/活性炭复合PCMs (b)和纯石蜡(c)的柱状样品在80℃下加热不同时间的泄漏测试照片
Fig.7  石蜡/TiO2/活性炭复合PCMs的超疏水性测试照片(a)滴加水滴后;(b)移除水滴后
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