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材料工程  2016, Vol. 44 Issue (11): 73-77    DOI: 10.11868/j.issn.1001-4381.2016.11.012
  材料与工艺 本期目录 | 过刊浏览 | 高级检索 |
锰锌铁氧体的低温合成及表征
赵海涛, 王俏, 刘瑞萍, 马瑞廷
沈阳理工大学 材料科学与工程学院, 沈阳 110159
Synthesis and Characterization of MnZn Ferrite at Low Temperature
ZHAO Hai-tao, WANG Qiao, LIU Rui-ping, MA Rui-ting
School of Materials Science and Engineering, Shenyang Ligong University, Shenyang 110159, China
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摘要 采用溶胶-凝胶自燃烧法在低温下一步合成了纯相尖晶石结构的锰锌铁氧体(Mn0.5Zn0.5Fe2O4)纳米颗粒。其结构、形貌和热分解过程分别采用X射线衍射仪(XRD)、扫描电镜(SEM)和TG-DSC分析仪进行了表征。结果表明:在pH=7.0、柠檬酸与金属离子摩尔比为1:1和柠檬酸的浓度为0.7mol/L的条件下,金属的硝酸盐和柠檬酸形成的干凝胶可通过自燃烧过程一步合成出平均粒径约为60nm的纯相Mn0.5Zn0.5Fe2O4铁氧体纳米颗粒。经过400℃煅烧后,颗粒粒径增大,衍射峰变窄,强度增加,晶型更趋于完整。
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赵海涛
王俏
刘瑞萍
马瑞廷
关键词 锰锌铁氧体溶胶-凝胶自燃烧纳米颗粒    
Abstract:Pure phase spinel ferrite nanoparticles (Mn0.5Zn0.5Fe2O4) were one-step synthesized by the sol-gel auto-combustion method at low temperature. The structural characteristics, morphology and thermal decomposition were characterized by X-ray Diffraction (XRD), Scanning Electron Microscope (SEM), TG-DSC analyzer, respectively. The results indicate that pure phase Mn0.5Zn0.5Fe2O4 ferrite nanoparticles of about 60nm in diameter can be directly synthesized after auto-combustion of the nitrate-citrate xerogel under the conditions of pH=7.0, R=1:1 and C(CA)=0.7 mol/L. The obtained nanoparticles show the diameter increases and the diffraction peak narrows but the strength increases after calcined at 400℃ which improves the crystal structure.
Key wordsMnZn ferrites    sol-gel    auto-combustion    nanoparticle
收稿日期: 2014-11-06      出版日期: 2016-11-22
中图分类号:  TG146.4+16  
通讯作者: 赵海涛(1976-),女,副教授,博士,现从事功能材料研究,联系地址:辽宁省沈阳市浑南新区南屏中路6号沈阳理工大学材料学院(110159),E-mail:zht95711@163.com     E-mail: zht95711@163.com
引用本文:   
赵海涛, 王俏, 刘瑞萍, 马瑞廷. 锰锌铁氧体的低温合成及表征[J]. 材料工程, 2016, 44(11): 73-77.
ZHAO Hai-tao, WANG Qiao, LIU Rui-ping, MA Rui-ting. Synthesis and Characterization of MnZn Ferrite at Low Temperature. Journal of Materials Engineering, 2016, 44(11): 73-77.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2016.11.012      或      http://jme.biam.ac.cn/CN/Y2016/V44/I11/73
[1] XIANG J, SHEN X Q, ZHU Y W. Effects of Ce3+ doping on the structure and magnetic properties of Mn-Zn ferrite fibers[J]. Rare Metals, 2009, 28(2): 151-155.
[2] 任平, 张俊喜, 李雪, 等. 钴掺杂量对Mn-Zn铁氧体结构和磁性质的影响[J]. 硅酸盐学报, 2011, 39(11): 1882-1886. REN P, ZHANG J X, LI X, et al. Influence of Co-doping content on the structure and magnetic properties of Mn-Zn ferrites[J]. Journal of the Chinese Ceramic Society, 2011, 39(11): 1882-1886.
[3] KOSA A, MAKOVEC D, ZNIDARSIC A, et al. Preparation of MnZn-ferrite with microemulsion technique[J]. Journal of the European Ceramic Society, 2004, 24:959-962.
[4] 刘献明, 付绍云, 肖红梅, 等. 聚合-热解法制备Co0.2Zn0.2Mn0.6Fe2O4纳米颗粒及其表征[J].金属学报, 2006, 42(5): 497-499. LIU X M, FU S Y, XIAO H M, et al. Preparation of Co0.2Zn0.2Mn0.6Fe2O4 nanoparticles by a polymer-pyrolysis route and its characterzation[J]. Acta Metallurgica Sinica, 2006, 42(5): 497-499.
[5] SONG J, WANG L X, XU N C, et al. Microwave electromagnetic and absorbing properties of Dy3+ doped MnZn ferrites[J]. Journal of Rare Earths, 2010, 28(3): 451-455.
[6] 孙兵, 杨文达, 沈洪庆, 等. 锰锌铁氧体的制备工艺研究进展[J]. 电子元件与材料, 2013, 32(9): 1-4. SUN B, YANG W D, SHEN H Q, et al. Research progress of preparation technology of Mn-Zn ferrites[J]. Elecronic Components and Materials, 2013, 32(9): 1-4.
[7] 雷伟, 刘永生, 徐娟, 等. 锰锌铁氧体的制备研究进展[J]. 功能材料与器件学报, 2014, 20(6): 235-241. LEI W,LIU Y S,XU J, et al. Research progress of preparation technology of Mn-Zn ferrites[J]. Journal of Functional Materials and Devices, 2014, 20(6): 235-241.
[8] 齐西伟, 周济, 岳振星, 等. 溶胶凝胶自燃烧法合成Mn0.6Cu0.2Zn0.2O(Fe2O3)0.98纳米晶铁氧体及其磁性能研究[J]. 硅酸盐学报, 2003, 31(2): 138-142. QI X W, ZHOU J, YUE Z X, et al. Synthesis of nanocrystalline Mn0.6Cu0.2Zn0.2O(Fe2O3)0.98ferrite by sol-gel auto combustion method and characterzation of its magnetic properties[J]. Journal of the Chinese Ceramic Society, 2003, 31(2): 138-142.
[9] 彭会芬, 侯强, 张新梅, 等. 沉淀剂对Mn-Zn铁氧体纳米粒子磁性能的影响[J]. 人工晶体学报, 2014, 43(1): 111-115. PENG H F, HOU Q, ZHANG X M, et al. Effect of precipitants on magnetic properties of Mn-Zn ferrite nanoparticles[J]. Journal of Synthetic Crystals, 2014, 43(1): 111-115.
[10] LI D G, CHEN C, RAO W, et al. Preparation and microwave absorption properties of polyaniline/Mn0.8Zn0.2Fe2O4 nanocomposite in 2-18 GHz[J]. J Mater Sci: Mater Electron, 2014, 25:76-81.
[11] DONG C H, WANG G X, SHI L, et al. Investigation of the thermal stability of Mn ferrite particles synthesized by a modified co-precipitation method[J]. Science China Physics, Mechanics & Astronomy, 2013, 56(3): 568-572.
[12] FREIRE R M, FREITAS P G, RIBEIRO T S, et al. Effect of solvent composition on the structural and magnetic properties of MnZn ferrite nanoparticles obtained by hydrothermal synthesis[J]. Microfluid Nanofluid, 2014, 17: 233-244.
[13] RAMESHBABU R, RAMESH R, KANAGESAN S, et al. Synthesis of superparamagnetic ZnFe2O4 nanoparticle by surfactant assisted hydrothermal method[J]. J Mater Sci: Mater Electron, 2013, 24:4279-4283.
[14] MAKOVEC D, DROFENIK M, ZNIDARSIC A. Sintering of MnZn-ferrite powders prepared by hydrothermal reactions between oxides[J]. Journal of the European Ceramic Society, 2001, 21:1945-1949.
[15] ZHANG Q Y, ZHENG P, ZHENG L, et al. Effect of Co-substitution on the structure and magnetic properties of MnZn power ferrite[J]. J Electroceram, 2014, 32:230-233.
[16] TASAKALOUDI V, HOLZ D, ZASPALIS V. The effect of externally applied uniaxial compressive stress on the magnetic properties of power MnZn-ferrites[J]. J Mater Sci, 2013, 48:3825-3833.
[17] 陈燕华, 丘泰. 共沉淀法制备锰锌铁氧体粉工艺条件研究[J]. 材料导报, 2006, 20(7): 347-348. CHEN Y H, QIU T. Study on the techniques of preparation of MnZn ferrites with Co-precipitation Method[J]. Materials Review, 2006, 20(7): 347-348.
[18] SIVAKUMAR P, RAMESH R, RAMANAND A, et al. Preparation and properties of nickel ferrite(NiFe2O4) nanoparticles via sol-gel auto-combustion method[J]. Materials Research Bulletin, 2011, 46:2204-2207.
[19] AGHAV P S, DHAGE V N, MANE M L, et al. Effect of aluminum substitution on the structural and magnetic properties of cobalt ferrite synthesized by sol-gel auto combustion process[J]. Physica B, 2011, 406: 4350-4354.
[20] LIU J L, ZENG Y W, GUO C J, et al. One-step synthesis of barium hexaferrite nano-powders via microwave-assisted sol-gel auto-combustion[J]. Journal of the European Ceramic Society, 2010, 30: 993-997.
[21] ZHANG W, FANG C X, YIN W H, et al. One-step synthesis of yttrium orthoferrite nanocrystals via sol-gel auto-combustion and their structural and magnetic characteristics[J]. Materials Chemistry and Physics, 2013, 137: 877-883.
[22] 黄凤群. 溶胶-凝胶自燃烧法制备纳米软磁铁氧体及其磁性研究[D]. 天津: 天津大学, 2012. HUANG F Q. Magnetic properties of nanosize soft magnetic ferrites synthetized by sol-gel auto-combustion[D]. Tianjin: Tianjin University, 2012.
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