脉冲微孔喷射法单分散球形微粒子的制备及其应用

doi:10.11868/j.issn.1001-4381.2017.000242

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摘要

介绍了用于制备单分散高精度球形微粒子的脉冲微孔喷射技术，说明了该技术的工作原理，根据所能制备材料的熔点不同，分为低熔点压片式喷射设备和高熔点传动杆式喷射设备。脉冲微孔法制备出的粒子具有单分散，粒径均一可控，圆球度高，热历史一致的优点，通过介绍该方法制备的粒子在电子封装、生物工程、微成型、金属熔滴的快速凝固分析、增材制造等领域的应用，说明了该技术蕴涵的巨大潜力。可以预见，随着研究的深入，该技术因其独有的特点将具有更广阔的发展。

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	董伟
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关键词 ：脉冲微孔喷射法, 单分散粒子, 球形, 粒径可控

Abstract：

A novel technology called pulsated orifice ejection method(POEM) and used for preparing mono-sized and high-precision spherical micro particles was introduced in this article. The working principle of the technique was illustrated and it was in two modes:low-melting point diaphragm mode and high-melting point rod mode, depending on the different melting points of materials. The particles prepared by POEM have the advantages of mono-sized, uniform and controllable particle size, high sphericity, and consistent thermal history. By introducing the application of particles prepared by this method, showing the huge application prospects of this technology in electronic packaging, bioengineering, micro-fabrication, rapid solidification analysis of metal droplets, additive manufacturing and so on.With the development of POEM, this technology is predicted to have wider prospects due to its unique characteristics.

Key words： pulsated orifice ejection method mono-sized particle spherical controllable particle size

收稿日期: 2017-03-06 出版日期: 2018-02-01

中图分类号:

TB34

基金资助:辽宁省自然科学基金(201602150);中央高校基本科研业务费专项资金(DUT15ZD239);国家自然科学基金(51571050)

通讯作者: 董伟 E-mail: w-dong@dlut.edu.cn

作者简介: 董伟(1965-), 男, 副教授, 博士生导师, 现从事单分散微米级粒子制备与液滴沉积成型方向的研究, 联系地址:辽宁省大连市甘井子区凌工路2号大连理工大学新三束实验室208(116024),E-mail: w-dong@dlut.edu.cn

引用本文:

董伟, 李文畅, 康世薇, 许富民, 韩阳, 白兆丰. 脉冲微孔喷射法单分散球形微粒子的制备及其应用[J]. 材料工程, 2018, 46(2): 142-151.
Wei DONG, Wen-chang LI, Shi-wei KANG, Fu-min XU, Yang HAN, Zhao-feng BAI. Fabrication and Application of Mono-sized Spherical Micro Particles by Pulsated Orifice Ejection Method. Journal of Materials Engineering, 2018, 46(2): 142-151.

链接本文:

http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2017.000242 或 http://jme.biam.ac.cn/CN/Y2018/V46/I2/142

Fig.1 压片式脉冲微孔喷射法示意图^[18]

Fig.2 传动杆式脉冲微孔喷射法示意图

Fig.3 锡球和铜核球在电子封装中的对比图

Fig.4 POEM制备的Cu粒子的SEM图像(a)及其粒径分布(b)

Fig.5 脉冲微孔喷射法制备β-TCP粒子原理图

Fig.6 POEM制备的β-TCP粒子的SEM图像(a)及其粒径分布(b)

Fig.7 POEM制备的[(Fe_0.5Co_0.5)_0.75B_0.2Si_0.05]₉₆Nb₄金属玻璃粒子的SEM图像

Fig.8 [(Fe_0.5Co_0.5)_0.75B_0.2Si_0.05]₉₆Nb₄金属玻璃粒子的非晶特性
(a)XRD图像；(b)TEM图像

Fig.9 [(Fe_0.5Co_0.5)_0.75B_0.2Si_0.05]₉₆Nb₄金属玻璃粒子的冷却速率和直径的关系

Fig.10 [(Fe_0.5Co_0.5)_0.75B_0.2Si_0.05]₉₆Nb₄金属玻璃粒子制备的齿轮(a)及其TEM图像(b)^[52]

Fig.11 Bi-Ga偏晶合金核壳结构

Fig.12 POEM制备的Al粒子的SEM图像

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