Please wait a minute...
 
材料工程  2018, Vol. 46 Issue (7): 1-11    DOI: 10.11868/j.issn.1001-4381.2017.001333
  3D打印技术专栏 本期目录 | 过刊浏览 | 高级检索 |
石墨烯/聚合物基复合材料3D打印成型研究进展
许婧, 邢悦, 郝思嘉, 任志东, 杨程
中国航发北京航空材料研究院 石墨烯及应用研究中心, 北京 100095
Research Progress in Graphene/Polymer Composites Processing Using 3D Printing Technology
XU Jing, XING Yue, HAO Si-jia, REN Zhi-dong, YANG Cheng
Research Center of Graphene Applications, AECC Beijing Institute of Aeronautical Materials, Beijing 100095, China
全文: PDF(1452 KB)   HTML()
输出: BibTeX | EndNote (RIS)      
摘要 石墨烯因其优异的特性,被广泛用于制备聚合物基复合材料,而3D打印作为一种新兴的成型加工方式,正越来越多地应用到石墨烯/聚合物基复合材料的成型制造当中。本文介绍石墨烯/聚合物基复合材料的溶液混合、熔融混合以及原位聚合三种主要制备方式,重点论述喷墨打印成型、熔融沉积成型、立体光固化成型、选择性激光烧结等目前国内外用于石墨烯/聚合物基复合材料成型的3D打印方式及其各自的优势和劣势,以及3D打印成型的石墨烯/聚合物基复合材料制件在电子、能源、生物医学和航空航天等领域的应用,最后指出可打印性好、石墨烯分散均匀、功能特性优异的石墨烯/聚合物基复合材料的研制将会是未来该方向的研究重点。
服务
把本文推荐给朋友
加入引用管理器
E-mail Alert
RSS
作者相关文章
许婧
邢悦
郝思嘉
任志东
杨程
关键词 石墨烯聚合物复合材料3D打印成型应用    
Abstract:Graphene is widely used in the preparation of polymer matrix composites because of its excellent properties. 3D printing, as an emerging technology, is increasingly applied to the shaping and processing of graphene/polymer composites. In this paper, three kinds of main preparation methods of graphene/polymer composites which are solution mixing, melt blending, and in-situ polymerization were introduced. 3D printing methods and the advantages and disadvantages of inkjet printing, fused deposition modeling (FDM), stereolithography (SLA) and selective laser sintering (SLS) as well as their characteristics were summarized. Besides, the applications of 3D-printed graphene/polymer composites in electronics, energy, biomedical and aerospace were reviewed. Finally, it was pointed out that the further research in this area would be focused on the fabrication of graphene/polymer composites which have good printability, homogeneous dispersed graphene, and excellent functional characteristics.
Key wordsgraphene    polymer    composites    3D printing    processing    application
收稿日期: 2017-10-30      出版日期: 2018-07-20
中图分类号:  TB324  
通讯作者: 杨程(1978-),女,研究员,博士,主要从事石墨烯的制备和应用研究,联系地址:北京市81信箱72分箱(100095),E-mail:chengyang_78@126.com     E-mail: chengyang_78@126.com
引用本文:   
许婧, 邢悦, 郝思嘉, 任志东, 杨程. 石墨烯/聚合物基复合材料3D打印成型研究进展[J]. 材料工程, 2018, 46(7): 1-11.
XU Jing, XING Yue, HAO Si-jia, REN Zhi-dong, YANG Cheng. Research Progress in Graphene/Polymer Composites Processing Using 3D Printing Technology. Journal of Materials Engineering, 2018, 46(7): 1-11.
链接本文:  
http://jme.biam.ac.cn/CN/10.11868/j.issn.1001-4381.2017.001333      或      http://jme.biam.ac.cn/CN/Y2018/V46/I7/1
[1] CHAE H K,SIBERIO-PÉREZ D Y,KIM J,et al.A route to high surface area,porosity and inclusion of large molecules in crystals[J].Nature,2004,427(6974):523-527.
[2] GEIM A K,NOVOSELOV K S.The rise of graphene[J].Nature Materials,2007,6(3):183-191.
[3] NOVOSELOV K S,GEIM A K,MOROZOV S V,et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[4] BALANDIN A A,GHOSH S,BAO W,et al.Superior thermal conductivity of single-layer graphene[J].Nano Letters,2008,8(3):902-907.
[5] NETO C,ANTONIO H.Another spin on graphene[J].Science,2011,332(6027):315-316.
[6] XU D,WANG Z.Role of multi-wall carbon nanotube network in composites to crystallization of isotactic polypropylene matrix[J].Polymer,2008,49(1):330-338.
[7] PENG H,SUN X,CAI F,et al.Electrochromatic carbon nanotube/polydiacetylene nanocomposite fibres[J].Nature Nanotechnology,2009,4(11):738-742.
[8] TIBBETTS G G,LAKE M L,STRONG K L,et al.A review of the fabrication and properties of vapor-grown carbon nanofiber/polymer composites[J].Composites Science & Technology,2007,67(7):1709-1718.
[9] STANKOVICH S,DIKIN D A,RUOFF R S,et al.Graphene-based composite materials[J].Nature, 2006,442:282-286.
[10] YOUSEFI N,LIN X,ZHENG Q,et al.Simultaneous in situ reduction,self-alignment and covalent bonding in graphene oxide/epoxy composites[J].Carbon,2013,59(7):406-417.
[11] SI J,LI J,WANG S,et al.Enhanced thermal resistance of phenolic resin composites at low loading of graphene oxide[J].Composites Part A,2013,54(4):166-172.
[12] 郑辉东, 欧忠星, 郑玉婴,等. 功能石墨烯/热塑性聚氨酯复合材料膜的制备及性能[J]. 材料工程, 2016, 44(11):114-119. ZHEN H D,OU Z X,ZHEN Y Y,et al.Preparation and properties of functional graphene/thermoplastic polyurethane composite film[J]. Journal of Materials Engineering,2016,44(11):114-119.
[13] GOYANES A,WANG J,BUANZ A,et al.3D printing of medicines:engineering novel oral devices with unique design and drug release characteristics[J].Molecular Pharmaceutics,2015,12(11):4077-4084.
[14] 黄丹, 朱志华, 耿海滨,等. 5A06铝合金TIG丝材-电弧增材制造工艺[J]. 材料工程, 2017, 45(3):66-72. HUANG D, ZHU Z H, GENG H B, et al.TIG wire and arc additive manufacturing of 5A06 aluminum alloy[J]. Journal of Materials Engineering, 2017, 45(3):66-72.
[15] GVNTHER D,HEYMEL B,GVNTHER J F,et al.Continuous 3D-printing for additive manufacturing[J].Rapid Prototyping Journal,2014,20(4):320-327.
[16] 陈硕平,易和平,罗志虹,等.高分子3D打印材料和打印工艺[J].材料导报,2016,30(7):54-59. CHEN S P,YI H P,LUO Z H,et al.The 3D printing polymers and their printing technologies[J].Materials Review,2016,30(7):54-59.
[17] PAREDES J I,VILLARRODIL S,MARTÍNEZALONSO A,et al.Graphene oxide dispersions in organic solvents[J].Langmuir the ACS Journal of Surfaces & Colloids,2008,24(19):10560-10564.
[18] XU Y,HONG W,BAI H,et al.Strong and ductile poly(vinyl alcohol)/graphene oxide composite films with a layered structure[J].Carbon,2009,47(15):3538-3543.
[19] YUAN M,ERDMAN J,TANG C,et al.High performance solid polymer electrolyte with graphene oxide nanosheets[J].RSC Advances,2014,4(103):59637-59642.
[20] YANG C,HAO S J,DAI S L,et,al.Nanocomposites of poly(vinylidene fluoride)-controllable hydroxylated/carboxylated graphene with enhanced dielectric performance for large energy density capacitor[J].Carbon,2017,117:301-302.
[21] 杨程,陈宇滨,田俊鹏,等.功能化石墨烯的制备及应用研究进展[J].航空材料学报,2016,36(3):40-56. YANG C,CHEN Y B,TIAN J P,et al.Development in preparation and application of graphene functionalization[J].Journal of Aeronautical Materials,2016,36(3):40-56.
[22] JOHNSON D W,DOBSON B P,COLEMAN K S.A manufacturing perspective on graphene dispersions[J].Current Opinion in Colloid & Interface Science,2015,20(5):367-382.
[23] REN P G,YAN D X,CHEN T,et al.Improved properties of highly oriented graphene/polymer nanocomposites[J].Journal of Applied Polymer Science,2011,121(6):3167-3174.
[24] WAN Y J,TANG L C,GONG L X,et al.Grafting of epoxy chains onto graphene oxide for epoxy composites with improved mechanical and thermal properties[J].Carbon,2014,69(2):467-480.
[25] WEI X,LI D,JIANG W,et al.3D printable graphene composite[J].Scientific Reports,2015,5:11181-11188.
[26] KUMAR P,YU S,SHAHZAD F,et al.Ultrahigh electrically and thermally conductive self-aligned graphene/polymer composites using large-area reduced graphene oxides[J].Carbon,2016,101:120-128.
[27] ZENG C,LU S,XIAO X,et al.Enhanced thermal and mechanical properties of epoxy composites by mixing noncovalently functionalized graphene sheets[J].Polymer Bulletin,2015,72(3):453-472.
[28] LI P,CHEN X,ZENG J B,et al.Enhancement of interfacial interaction between poly(vinyl chloride) and zinc oxide modified reduced graphene oxide[J].RSC Advances,2016,6(7):5784-5791.
[29] CHATTERJEE S,NVESCH F A,CHU B T.Comparing carbon nanotubes and graphene nanoplatelets as reinforcements in polyamide 12 composites[J].Nanotechnology,2011,22(27):275714.
[30] YOU F,WANG D,CAO J,et al.In situ thermal reduction of graphene oxide in a styrene-ethylene/butylene-styrene triblock copolymer via melt blending[J].Polymer International,2013,63(1):93-99.
[31] KIM H,MIURA Y,MACOSKO C W.Graphene/polyurethane nanocomposites for improved gas barrier and electrical conductivity[J].Chemistry of Materials,2010,22(11):3441-3450.
[32] ZHANG H B,YAN Q,ZHENG W G,et al.Tough graphene-polymer microcellular foams for electromagnetic interference shielding[J].ACS Applied Materials & Interfaces,2011,3(3):918-924.
[33] KIM H,MACOSKO C W.Processing-property relationships of polycarbonate/graphene composites[J].Polymer,2009,50(15):3797-3809.
[34] ISTRATE O M,PATON K R,KHAN U,et al.Reinforcement in melt-processed polymer-graphene composites at extremely low graphene loading level[J].Carbon,2014,78(18):243-249.
[35] WANG H,XIE G,ZHU Z,et al.Enhanced tribological performance of the multi-layer graphene filled poly(vinyl chloride)composites[J].Composites Part A,2014,67:268-273.
[36] HSIAO M C,LIAO S H,LIN Y F,et al.Preparation and characterization of polypropylene-graft-thermally reduced graphite oxide with an improved compatibility with polypropylene-based nanocomposite[J].Nanoscale,2011,3(4):1516-1522.
[37] WANG J Y,YANG S Y,HUANG Y L,et al.Preparation and properties of graphene oxide/polyimide composite films with low dielectric constant and ultrahigh strength via in situ polymerization[J].Journal of Materials Chemistry,2011,21(35):13569-13575.
[38] POTTS J R,SUN H L,ALAM T M,et al.Thermomechanical properties of chemically modified graphene/poly(methyl methacrylate)composites made by in situ polymerization[J].Carbon,2011,49(8):2615-2623.
[39] CHEN Z,LU H.Constructing sacrificial bonds and hidden lengths for ductile graphene/polyurethane elastomers with improved strength and toughness[J].Journal of Materials Chemistry,2012,22(25):12479-12490.
[40] LI J,XIE H,LI Y,et al.Electrochemical properties of graphene nanosheets/polyaniline nanofibers composites as electrode for supercapacitors[J].Journal of Power Sources,2011,196(24):10775-10781.
[41] GUO Y,BAO C,SONG L,et al.In situ polymerization of graphene,graphite oxide,and functionalized graphite oxide into epoxy resin and comparison study of on-the-flame behavior[J].Industrial & Engineering Chemistry Research,2011,50(13):7772-7783.
[42] ESWARAIAH V,SANKARANARAYANAN V,RAMAPRABHU S.Functionalized graphene-PVDF foam composites for EMI shielding[J].Macromolecular Materials & Engineering,2011,296(10):894-898.
[43] PATOLE A S,PATOLE S P,KANG H,et al.A facile approach to the fabrication of graphene/polystyrene nanocomposite by in situ microemulsion polymerization[J].Journal of Colloid & Interface Science,2010,350(2):530-537.
[44] ALDOSARI M A,OTHMAN A A,ALSHARAEH E H.Synthesis and characterization of the in situ bulk polymerization of PMMA containing graphene sheets using microwave irradiation[J].Molecules,2013,18(3):3152-3167.
[45] LI J,SOLLAMI D S,ZHANG P,et al.Scalable fabrication and integration of graphene micro-supercapacitors through full inkjet printing[J].ACS Nano,2017,11(8):8249-8256.
[46] DODOO A D,HOWE C T,HU G,et al.Inkjet-printed graphene electrodes for dye-sensitized solar cells[J].Carbon,2016,105:33-41.
[47] LIM S,KANG B,KWAK D,et al.Inkjet-printed reduced graphene oxide/poly(vinyl alcohol)composite electrodes for flexible transparent organic field-effect transistors[J].Journal of Physical Chemistry C,2012,116(13):7520-7525.
[48] POSPISIL J,SCHMIEDOVA V,ZMESKAL O,et al.Electrical properties of graphene oxide layers prepared by material inkjet printing[J].Key Engineering Materials,2016,674:109-114.
[49] GARCÍA-TUÑÓN E,BARG S,FRANCO J,et al.Printing in three dimensions with graphene[J].Advanced Materials,2015,27(10):1688-1693.
[50] JABARI E,TOYSERKANI E.Micro-scale aerosol-jet printing of graphene interconnects[J].Carbon,2015,91:321-329.
[51] CHI K,ZHANG Z,XI J,et al.Freestanding graphene paper supported three-dimensional porous graphene-polyaniline nanocomposite synthesized by inkjet printing and in flexible all-solid-state supercapacitor[J].ACS Applied Materials & Interfaces,2014,6(18):16312-16319.
[52] JAKUS A E,SECOR E B,RUTZ A L,et al.Three-dimensional printing of high-content graphene scaffolds for electronic and biomedical applications[J].ACS Nano,2015,9(4):4636-4648.
[53] WEI X,LI D,WEI J,et al.3D printable graphene composite[J].Scientific Reports,2015,5:11181-11188.
[54] CHEN Q,MANGADLAO J D,WALLAT J,et al.3D printing biocompatible polyurethane/poly(lactic acid)/graphene oxide nanocomposites:anisotropic properties[J].ACS Applied Materials & Interfaces, 2017,9(4):4015-4023.
[55] ZHU D,REN Y,LIAO G,et al.Thermal and mechanical properties of polyamide 12/graphene nanoplatelets nanocomposites and parts fabricated by fused deposition modeling[J].Journal of Applied Polymer Science, 2017,134(39):45332.
[56] ZHANG D,CHI B,LI B,et al.Fabrication of highly conductive graphene flexible circuits by 3D printing[J].Synthetic Metals,2016,217:79-86.
[57] SAYYAR S,CORNOCK R,MURRAY E,et al.Extrusion printed graphene/polycaprolactone composites for tissue engineering[J].Materials Science Forum,2014,773:496-502.
[58] ZHOU X,NOWICKI M,CUI H,et al.3D bioprinted graphene oxide-incorporated matrix for promoting chondrogenic differentiation of human bone marrow mesenchymal stem cells[J].Carbon,2017,116:615-624.
[59] WANG L,NI X.The effect of the inorganic nanomaterials on the UV-absorption,rheological and mechanical properties of the rapid prototyping epoxy-based composites[J].Polymer Bulletin,2016:1-17.
[60] GALLARDO A,PEREYRA Y,MARTÍNEZCAMPOS E,et al.Facile one-pot exfoliation and integration of 2D layered materials by dispersion in a photocurable polymer precursor[J].Nanoscale,2017,9(30):10590-10595.
[61] ZHU W,HARRIS B T,ZHANG L G,et al.Gelatin methacrylamide hydrogel with graphene nanoplatelets for neural cell-laden 3D bioprinting[C]//Conf Proc IEEE Eng Med Biol Soc.Piscataway:Engineering in Medicine & Biology Society,2016:4185.
[62] SHUAI C,FENG P,GAO C,et al.Graphene oxide reinforced poly(vinyl alcohol):nanocomposite scaffolds for tissue engineering applications[J].RSC Advances,2015,5(32):25416-25423.
[63] GAIKWAD S,TATE J,THEODOROPOULOU N,et al.Electrical and mechanical properties of PA11 blended with nanographene platelets using industrial twin-screw extruder for selective laser sintering[J].Journal of Composite Materials,2013,47(23):2973-2986.
[64] DAS S.Selective laser sintering of polymers and polymer-ceramic composites[J].Virtual Prototyping & Bio Manufacturing in Medical Applications,2008:229-260.
[65] SIRRINGHAUS H,KAWASE T,FRIEND R H,et al.High-resolution inkjet printing of all-polymer transistor circuits[J].Science,2000,290(5499):2123-2126.
[66] 王楠, 燕绍九, 彭思侃,等. 3D打印石墨烯制备技术及其在储能领域的应用研究进展[J]. 材料工程, 2017, 45(12):112-115. WANG N, YAN S J, PENG S K, et al.Research progress on 3D printed graphene materials synthesis technology and its application in energy storage field[J].Journal of Materials Engineering, 2017, 45(12):112-115.
[67] SINGH M,HAVERINEN H M,DHAGAT P,et al.Inkjet printing-process and its applications[J].Advanced Materials,2010,22(6):673-685.
[68] WENDEL B,RIETZEL D,KVHNLEIN F,et al.Additive processing of polymers[J].Macromolecular Materials & Engineering,2008,293(10):799-809.
[69] PADDUBSKAYA A,VALYNETS N,KUZHIR P,et al.Electromagnetic and thermal properties of three-dimensional printed multilayered nano-carbon/poly(lactic)acid structures[J].Journal of Applied Physics,2016,119(13):924-1186.
[70] SINGH R,SANDHU G S,PENNA R,et al.Investigations for thermal and electrical conductivity of ABS-graphene blended prototypes[J].Materials,2017,10(7):881-894.
[71] MELCHELS F P,FEIJEN J,GRIJPMA D W.A review on stereolithography and its applications in biomedical engineering[J].Biomaterials,2010,31(24):6121-6130.
[72] 王延庆, 沈竞兴, 吴海全. 3D打印材料应用和研究现状[J]. 航空材料学报, 2016, 36(4):89-98. WANG Y Q, SHEN J X, WU H Q. Application and research status of alternative materials for 3D-printing technology[J]. Journal of Aeronautical Materials,2016, 36(4):89-98.
[73] LEE W C,LIM C H,SHI H,et al.Origin of enhanced stem cell growth and differentiation on graphene and graphene oxide[J].ACS Nano,2011,5(9):7334-7341.
[74] MANAPAT J Z,MANGADLAO J D,TIU B D,et al.High-strength stereolithographic 3D printed nanocomposites:graphene oxide metastability[J].ACS Applied Materials & Interfaces,2017,9(11):100085-100093.
[75] LIN D,JIN S,ZHANG F,et al.3D stereolithography printing of graphene oxide reinforced complex architectures[J].Nanotechnology,2015,26(43):434003.
[76] KORHONEN H,SINH L H,LUONG N D,et al.Fabrication of graphene-based 3D structures by stereolithography[J].Physica Status Solidi,2016,213(4):982-985.
[77] GU D D,MEINERS W,WISSENBACH K,et al.Laser additive manufacturing of metallic components:materials,processes and mechanisms[J].International Materials Reviews,2012,57(3):133-164.
[78] ANNA M,MARIA T,KONSTANTY S,et al.PA-G composite powder for innovative additive techniques[J].Composites Theory and Practice,2015,15(3):152-157.
[79] 石晓东,王伟,金慧娇,等.石墨烯场效应晶体管的输运特性[J].科学通报,2017(14):1520-1526. SHI X D,WANG W,JIN H J,et al.Transport properties of graphene field effect transistors[J].Chinese Science Bulletin,2017(14):1520-1526.
[80] WANG Y,HUANG B C,ZHANG M,et al.Optimizing the fabrication process for high performance graphene field effect transistors[J].Microelectronics Reliability,2012,52(8):1602-1605.
[81] SCHWIERZ F.Graphene transistors[J].Nat Nanotech,2010,5:487-496.
[82] XIANG L,WANG Z,LIU Z,et al.Inkjet-printed flexible biosensor based on graphene field effect transistor[J].IEEE Sensors Journal,2016,16(23):8359-8364.
[83] SUN T,WANG Z L,SHI Z J,et al.Multilayered graphene used as anode of organic light emitting devices[J].Applied Physics Letters,2010,96(13):55-59.
[84] WU J,AGRAWAL M,BECERRIL H A,et al.Organic light-emitting diodes on solution-processed graphene transparent electrodes[J].ACS Nano,2010,4(1):43-48.
[85] RUDORFER A,TSCHERNER M,PALFINGER C,et al.A study on Aerosol Jet printing technology in LED module manufacturing[C]//Fifteenth International Conference on Solid State Lighting and LED-based Illumination Systems.Bellingham:SPIE,2016:99540E.
[86] HUANG L,HUANG Y,LIANG J,et al.Graphene-based conducting inks for direct inkjet printing of flexible conductive patterns and their applications in electric circuits and chemical sensors[J].Nano Research,2011,4(7):675-684.
[87] SECOR E B,PRABHUMIRASHI P L,PUNTAMBEKAR K,et al.Inkjet printing of high conductivity,flexible graphene patterns[J].Journal of Physical Chemistry Letters,2013,4(8):1347-1351.
[88] DU X,GUO P,SONG H,et al.Graphene nanosheets as electrode material for electric double-layer capacitors[J].Electrochimica Acta,2010,55(16):4812-4819.
[89] ZHU Y,MURALI S,STOLLER M D,et al.Microwave assisted exfoliation and reduction of graphite oxide for ultracapacitors[J].Carbon,2010,48(7):2118-2122.
[90] YAN J,WEI T,SHAO B,et al.Preparation of a graphene nanosheet/polyaniline composite with high specific capacitance[J].Carbon,2010,48(2):487-493.
[91] AN J,LIU J,ZHOU Y,et al.Polyaniline-grafted graphene hybrid with amide groups and its use in supercapacitors[J].Journal of Physical Chemistry C,2012,116(37):19699-19708.
[92] YU D,DAI L.Self-assembled graphene/carbon nanotube hybrid films for supercapacitors[J].Journal of Physical Chemistry Letters,2015,1(2):467-470.
[93] LI J,SOLLAMI D S,ZHANG P,et al.Scalable fabrication and integration of graphene micro-supercapacitors through full inkjet printing[J].ACS Nano,2017,11(8):8249-8256.
[94] LI T,GAO L.A high-capacity graphene nanosheet material with capacitive characteristics for the anode of lithium-ion batteries[J].Journal of Solid State Electrochemistry,2012,16(2):557-561.
[95] BHASKAR A,DEEPA M,RAO T N,et al.Enhanced nanoscale conduction capability of a MoO2/graphene composite for high performance anodes in lithium ion batteries[J].Journal of Power Sources,2012,216(11):169-178.
[96] FU K,WANG Y,YAN C,et al.Graphene oxide-based electrode inks for 3D-printed lithium-ion batteries[J].Advanced Materials,2016,28(13):2587-2594.
[97] 陈冠雄,谈紫琪,赵元,等.面向能源领域的石墨烯研究[J].中国科学:化学,2013,43(6):704-715. CHEN G X,TAN Z Q,ZHAO Y,et al.Applications of graphene for energy storage and conversion[J].Scientia Sinica Chimica,2013,43(6):704-715.
[98] DODOO A D,HOWE R C T,HU G,et al.Inkjet-printed graphene electrodes for dye-sensitized solar cells[J].Carbon,2016,105:33-41.
[99] QU L,LIU Y,BAEK J B,et al.Nitrogen-doped graphene as efficient metal-free electrocatalyst for oxygen reduction in fuel cells[J].ACS Nano,2010,4(3):1321-1326.
[100] JAFRI R I,RAJALAKSHMI N,RAMAPRABHU S.Nitrogen doped graphene nanoplatelets as catalyst support for oxygen reduction reaction in proton exchange membrane fuel cell[J].Journal of Materials Chemistry,2010,20(34):7114-7117.
[101] HU W,PENG C,LUO W,et al.Graphene-based antibacterial paper[J].ACS Nano,2010,4(7):4317-4323.
[102] LIU Z,ROBINSON J T,SUN X,et al.PEGylated nanographene oxide for delivery of water-insoluble cancer drugs[J].Journal of the American Chemical Society,2008,130(33):10876-10887.
[103] ZHANG L,XIA J,ZHAO Q,et al.Functional graphene oxide as a nanocarrier for controlled loading and targeted delivery of mixed anticancer drugs[J].Small,2010,6(4):537-544.
[104] YANG K,ZHANG S,ZHANG G,et al.Graphene in mice:ultrahigh in vivo tumor uptake and efficient photothermal therapy[J].Nano Letters,2010,10(9):3318-3323.
[105] ZHANG L,LIU W,YUE C,et al.A tough graphene nanosheet/hydroxyapatite composite with improved in vitro,biocompatibility[J].Carbon,2013,61(11):105-115.
[106] RUIZ O N,FERNANDO K A,WANG B,et al.Graphene oxide:a nonspecific enhancer of cellular growth[J].ACS Nano,2011,5(10):8100-8107.
[107] ZHU W, HARRIS B T, ZHANG L G, et al. Gelatin methacrylamide hydrogel with graphene nanoplatelets for neural cell-laden 3D bioprinting[C]//Conf Proc IEEE Eng Med Biol Soc.Orlando:Engineering in Medicine & Biology Society, 2016:4185.
[108] 朱琳.新型碳纳米材料的特点与航空航天领域应用展望[J].冶金标准化与质量,2015(6):41-44. ZHU L.Characteristics of new type carbon nano material and its application in the field of aeronautics and astronautics[J].Metallurgical Standardization & Quality,2015(6):41-44.
[109] SIOCHI E J.Graphene in the sky and beyond[J].Nature Nanotechnology,2014,9(10):745-747.
[110] 邢悦,郝思嘉,陈宇滨,等.浅谈石墨烯性能及前沿应用[J].新材料产业,2016(10):24-30. XING Y,HAO S J,CHEN Y B,et al.Discussion on the performance and frontier application of graphene[J].Advanced Materials Industry,2016(10):24-30.
[111] 谢卫刚,赵东林,景磊,等.石墨烯/环氧树脂复合材料的制备与力学性能[J].高分子材料科学与工程,2012,28(9):129-132. XIE W G,ZHAO D L,JING L,et al.Preparation and mechanical properties of graphene reinforced epoxy resin matrix composites[J].Polymer Materials Science & Engineering,2012,28(9):129-132.
[112] WANG X,JIN J,SONG M.An investigation of the mechanism of graphene toughening epoxy[J].Carbon, 2013,65(6):324-333.
[113] 陈智明,林起浪,蔡秋红,等.氧化石墨烯/双马来酰亚胺树脂纳米复合材料的制备及性能[J].高分子材料科学与工程,2012,28(11):169-172. CHEN Z M,LIN Q L,CAI Q H,et al.Preparation and properties of graphene oxide/bismaleimide resin nanocomposites[J].Polymer Materials Science & Engineering,2012,28(11):169-172.
[114] LIU M,DUAN Y,WANG Y,et al.Diazonium functionalization of graphene nanosheets and impact response of aniline modified graphene/bismaleimide nanocomposites[J].Materials & Design,2014,53(1):466-474.
[115] ZHOU J,YAO Z,CHEN Y,et al.Mechanical and thermal properties of graphene oxide/phenolic resin composite[J].Polymer Composites,2013,34(8):1245-1249.
[116] 王立娜,陈成猛,杨永岗,等.氧化石墨烯-酚醛树脂薄膜的制备及性能研究[J].材料导报,2010,24(18):54-56. WANG L N,CHEN C M,YANG Y G,et al.The preparation and properties of graphene oxide sheets/phenolic resin composites[J].Materials Review,2010,24(18):54-56.
[117] 张永刚.碳纤维表面上浆剂和氧化石墨烯改性研究[D].北京:中国科学院大学,2015. ZHANG Y G.Study on carbon fiber surface sizing agent and its functionalization by graphene oxide[D].Beijing:University of Chinese Academy of Sciences,2015.
[118] HUANG S Y,WU G P,CHEN C M,et al.Electrophoretic deposition and thermal annealing of a graphene oxide thin film on carbon fiber surfaces[J].Carbon,2013,52(2):613-616.
[119] ROKNI H,LU W.Effect of graphene layers on static pull-in behavior of bilayer graphene/substrate electrostatic microactuators[J].Journal of Microelectromechanical Systems,2013,22(3):553-559.
[120] VERMA M,VERMA P,DHAWAN S K,et al.Tailored graphene based polyurethane composites for efficient electrostatic dissipation and electromagnetic interference shielding applications[J].RSC Advances,2015,5(118):97349-97358.
[121] GAGNÉ M,THERRIAULT D.Lightning strike protection of composites[J].Progress in Aerospace Sciences, 2014,64:1-16.
[122] AMIRSARDARI Z,AGHDAM R M,SALAVATI N M,et al.Enhanced thermal resistance of GO/C/phenolic nanocomposite by introducing ZrB2 nanoparticles[J].Composites Part B Engineering,2015,76(21):174-179.
[123] LI Q,CHEN W,YAN W,et al.In situ solution polymerization for preparation of MDI-modified graphene/hyperbranched poly(ether imide) nanocomposites and their properties[J].RSC Advances,2015,6(1):716-729.
[124] PARK J M,KWON D J,WANG Z J,et al.Interfacial,fire retardancy,and thermal stability evaluation of graphite oxide (GO)-phenolic composites with different GO particle sizes[J].Composites Part B Engineering,2013,53(5):290-296.
[125] 王婵媛, 王希晰, 曹茂盛. 轻质石墨烯基电磁屏蔽材料的研究进展[J]. 材料工程, 2016, 44(10):109-118. WANG C Y, WANG X X, CAO M S. Progress in research on light weight graphene-based EMI shielding material[J]. Journal of Material Engineering, 2016, 44(10):109-118.
[126] LI Y,ZHAI W.Graphene nanocomposites for electromagnetic induction shielding[M]//Graphene-based polymer nanocomposites in electronics.Cham Switzerland:Springer International Publishing,2015:345-372.
[127] SINGH A P,GARG P,ALAM F,et al.Phenolic resin-based composite sheets filled with mixtures of reduced graphene oxide,γ-Fe2O3,and carbon fibers for excellent electromagnetic interference shielding in the X-band[J].Carbon,2012,50(10):3868-3875.
[1] 陈珂龙, 张桐, 崔溢, 王智勇. 超支化聚合物(HBPs)改性环氧树脂的研究进展[J]. 材料工程, 2019, 47(7): 11-18.
[2] 王晨, 燕绍九, 南文争, 陈翔. 表面活性剂对高浓度石墨烯水分散液制备的影响[J]. 材料工程, 2019, 47(7): 50-56.
[3] 王桂芳, 刘忠侠, 张国鹏. 球磨时间对热压烧结制备TiC-CoCrFeNi复合材料微观组织及力学性能的影响[J]. 材料工程, 2019, 47(6): 94-100.
[4] 崔超婕, 田佳瑞, 杨周飞, 金鹰, 董卓娅, 谢青, 张刚, 叶珍珍, 王瑾, 刘莎, 骞伟中. 石墨烯在锂离子电池和超级电容器中的应用展望[J]. 材料工程, 2019, 47(5): 1-9.
[5] 薛子明, 雷卫宁, 王云强, 钱海峰, 李奇林. 超临界条件下脉冲占空比对石墨烯复合镀层微观结构和性能的影响[J]. 材料工程, 2019, 47(5): 53-62.
[6] 尚楷, 武志红, 张路平, 王倩, 郑海康. 模板法制备MoSi2/竹炭复合材料及吸波性能[J]. 材料工程, 2019, 47(5): 122-128.
[7] 何宗倍, 张瑞谦, 付道贵, 李鸣, 陈招科, 邱邵宇. 不同界面SiC纤维束复合材料的拉伸力学行为[J]. 材料工程, 2019, 47(4): 25-31.
[8] 李亚锋, 礼嵩明, 黑艳伟, 邢丽英, 陈祥宝. 太阳辐照对芳纶纤维及其复合材料性能的影响[J]. 材料工程, 2019, 47(4): 39-46.
[9] 李曦. 二维和零维纳米材料协同增强的高性能纳米复合材料[J]. 材料工程, 2019, 47(4): 47-55.
[10] 王晨, 燕绍九, 南文争, 王继贤, 彭思侃. 高浓度石墨烯水分散液的制备与表征[J]. 材料工程, 2019, 47(4): 56-63.
[11] 卢子龙, 安立宝, 刘扬. 不同浓度硼掺杂石墨烯吸附多层金原子的第一性原理研究[J]. 材料工程, 2019, 47(4): 64-70.
[12] 李芹, 盛利成, 董丽敏, 张彦飞, 金立国. ZnCo2O4及ZnCo2O4/rGO复合材料的制备与电化学性能[J]. 材料工程, 2019, 47(4): 71-76.
[13] 张航, 路媛媛, 王涛, 鲁亚冉, 刘德健. 激光熔覆WC/H13-Inconel625复合材料的冲击韧性与磨损性能[J]. 材料工程, 2019, 47(4): 127-134.
[14] 李惠, 肖文龙, 张艺镡, 马朝利. 多重结构Ti-B4C/Al2024复合材料的组织和力学性能[J]. 材料工程, 2019, 47(4): 152-159.
[15] 史思涛, 陈畅, 郭政, 李国新, 伍勇华, 苏明周, 王会萌. 原料配比对多孔MgO/Fe-Cr-Ni复合材料性能的影响[J]. 材料工程, 2019, 47(4): 167-173.
Viewed
Full text


Abstract

Cited

  Shared   
  Discussed   
版权所有 © 2015《材料工程》编辑部
地址:北京81信箱44分箱 邮政编码: 100095
电话:010-62496276 E-mail:matereng@biam.ac.cn
本系统由北京玛格泰克科技发展有限公司设计开发 技术支持:support@magtech.com.cn